24182-36-3

Basic information

• Product Name: Benzene, [(1Z)-2-bromo-1,3-butadienyl]-
• Synonyms: (Z)-3-bromo-4-phenyl-1,3-butadiene;[(Z)-2-bromobuta-1,3-dienyl]benzene;(Z)-2-bromo-1-phenyl-1,3-butadiene;Benzene,[(1Z)-2-bromo-1,3-butadienyl];(Z)-(2-bromobuta-1,3-dien-1-yl)benzene;cis-3-bromo-4-phenyl-1,3-butadiene
• CAS NO: 24182-36-3
• Molecular Formula: C10H9Br
• Molecular Weight: 209.085
• Mol File: 24182-36-3.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Benzene, [(1Z)-2-bromo-1,3-butadienyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1Z)-2-bromo-1,3-butadienyl]-(24182-36-3)
• EPA Substance Registry System: Benzene, [(1Z)-2-bromo-1,3-butadienyl]-(24182-36-3)

Safety Data

• Hazardous Substances Data: 24182-36-3(Hazardous Substances Data)

Upstream product

• 33603-90-6 (2Z)-2-bromo-3-phenyl-2-propenal 
• 2065-66-9 methyl-triphenylphosphonium iodide 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 104-55-2 3-phenyl-propenal 
• 100-52-7 benzaldehyde 
• 40595-34-4 (E)-trimethyl(3-phenylallyl)silane 
• 97072-45-2 1-((E)-1-phenylbuta-1,3-dien-2-ylsulfonyl)benzene 
• 7436-90-0 2,2-dibromostyrene 
• 78389-90-9 vinyl zinc chloride 
• 7486-35-3 tri-n-butyl(vinyl)tin 

Downstream Products

• 109-74-0 propyl cyanide 
• 10416-67-8 N-(trimethylsilyl)phthalimide 
• 1352748-49-2 (3aS,8aR)-dimethyl 5-phenyl-1,3,3a,8a-tetrahydroazulene-2,2(6H)-dicarboxylate 
• 1352748-51-6 (3aR,8aR)-5-phenyl-2-tosyl-1,2,3,3a,6,8a-hexahydrocyclohepta[c]pyrrole 

Relevant articles and documents

Palladium-Catalyzed Asymmetric Tandem Denitrogenative Heck/Tsuji-Trost of Benzotriazoles with 1,3-Dienes

The asymmetric denitrogenative cycloaddition has emerged as a powerful tool to build chiral aza-heterocyles. However, only one example of asymmetric denitrogenative cycloaddition of benzotriazole with unsaturated hydrocarbons has been explored so far, bec

Transition-metal-free synthesis of vicinal triborated compounds and selective functionalisation of the internal C-B bond

1,2,3-Triborated compounds can be prepared by simple nucleophilic borylation of 1,3-dienes, without the assistance of metal catalysts. Selective functionalisation of the internal C-B bond of the 1,2,3-triborated compounds, through cross-coupling with aryl

Photochemical generation and structure of vinyl radicals

Photolysis of a series of E or Z stereoisomeric α-R-substituted bromostyrenes (R = CH3, F or CN) in methanol yields E and/ or Z stereoisomeric styrenes, which stem from the corresponding vinyl radicals. The results show that the α-Me vinyl radical is a rapidly equilibrating, bent structure, while the α-F vinyl radical is a stable bent species, in agreement with earlier thermal results. The α-CN vinyl radical is assigned as a rapidly inverting bent and not a linear species from the stereochemical results as a function of temperature. Stereochemical data for the α-C(H)=O system in diethyl ether indicate a stable bent vinyl radical as product forming species. The conclusions are supported by quantum chemical computations. Wiley-VCH Verlag GmbH & Co. KGaA.