24302-23-6

Basic information

• Product Name: (4R)-1-(1-hydroxy-1-methylethyl)-4-methylcyclohexene
• Synonyms: (4R)-1-(1-hydroxy-1-methylethyl)-4-methylcyclohexene
• CAS NO: 24302-23-6
• Molecular Weight: 154.252
• Mol File: 24302-23-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (4R)-1-(1-hydroxy-1-methylethyl)-4-methylcyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: (4R)-1-(1-hydroxy-1-methylethyl)-4-methylcyclohexene(24302-23-6)
• EPA Substance Registry System: (4R)-1-(1-hydroxy-1-methylethyl)-4-methylcyclohexene(24302-23-6)

Safety Data

• Hazardous Substances Data: 24302-23-6(Hazardous Substances Data)

Upstream product

• 99-86-5 1-methyl-4-isopropyl-1,3-cyclohexadiene 
• 120749-17-9 Ascaridol 
• 1023741-30-1 C₁₁H₂₀O₄S 
• 443883-74-7 2-isopropylidene-5-methylcyclohexanol 
• 89-82-7 pulegone 
• 22472-80-6 syn-(-)-pulegol 
• 68318-18-3 2-Benzenesulfinyl-2,6-dimethyl-1-oxa-spiro[2.5]octane 
• 4031-37-2 cis-1-isopropyl-4-methylcyclohex-2-ene-1,4-diol 
• 108-05-4 vinyl acetate 
• 529-02-2 cis-pulegol 
• 917-64-6 methyl magnesium iodide 
• 22273-97-8 methyl-4 cyclohexenyl-1 methyle cetone 
• 917-54-4 methyllithium 
• 498-81-7 p-menthan-8-ol 

Downstream Products

• 1187946-21-9 trimethyl[1-methyl-1-(4-methylcyclohex-1-enyl)ethoxy]silane 
• 94348-40-0 mentha-4⁽⁵⁾,8⁽⁹⁾-dien-3-ol 
• 94348-41-1 mentha-4⁽⁵⁾,8⁽⁹⁾-dien-3-ol 
• 212559-34-7 (1S,2R,5R)-2-(1-hydroxyethyl)-2,5-dimethylcyclohexanol 
• 212559-33-6 (3S,5R)-2-(1-hydroxy-1-methylethyl)-5-methylcyclohexen-1-ol 
• 43124-56-7 (+)-isoterpinolene 
• 62192-80-7 (R)-p-mentha-3,8-diene 

Relevant articles and documents

An efficient procedure for the 1,3-transposition of allylic alcohols based on lithium naphthalenide induced reductive elimination of epoxy mesylates

An efficient protocol for the 1,3-transposition of allylic alcohols has been developed. The method is based on the pretransformation of allylic alcohols into the corresponding epoxy mesylates, followed by the reductive elimination of the resulting epoxy mesylates by using lithium naphthalenide (LN) as a reducing agent. Georg Thieme Verlag Stuttgart.

A convergent synthesis of the spiroketal moiety of the HIV-1 protease inhibitors didemnaketals

The stereoselective synthesis of the spiroketal fragment 4a and its C1″-epimer 4b of the HIV-1 protease inhibitors didemnaketals has been carried out through multisteps from the natural (R)-(+)-pulegone, which involved the diastereoselective construction of four chiral carbon centers by intramolecular chiral induction.