24469-82-7Relevant articles and documents
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Mavrov,M.V. et al.
, (1965)
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Metal-catalyzed coupling reactions on an olefin template: The total synthesis of Bupleurynol
Antunes, Luis M.,Organ, Michael G.
, p. 6805 - 6808 (2007/10/03)
The naturally occurring polyacetylene Bupleurynol was synthesized in a convergent and stereospecific manner using a series of metal-mediated cross-coupling reactions. The synthesis demonstrates the utility of using a di-functional olefin template for the stereospecific synthesis of a disubstituted alkene product and its elaboration to a natural product target.