247210-85-1Relevant articles and documents
A dibenz[a,c]phenazine-supported N-heterocyclic carbene and its rhodium and iridium complexes
Tapu, Daniela,McCarty, Zachary,Hutchinson, Lauren,Ghattas, Christopher,Chowdhury, Mahatab,Salerno, John,Vanderveer, Donald
, p. 134 - 141 (2014)
A new polycyclic N-heterocyclic carbene featuring a fused dibenz[a,c]phenazine moiety was generated in situ from the corresponding tetrafluoroborate salt. The synthesis and NMR data of its corresponding precursors, its sulfur adduct and dimer are reported
An isolable iron(ii) bis(supersilyl) complex as an effective catalyst for reduction reactions
Arata, Shogo,Sunada, Yusuke
, p. 2891 - 2895 (2019/03/06)
An isolable 14-electron iron bis(supersilyl) complex, Fe[Si(SiMe3)3]2(THF)2, was successfully synthesized from the reaction of FeBr2 with K[Si(SiMe3)3] and its structure was unambiguously determined by single-crystal X-ray diffraction analysis. The complex is coordinatively unsaturated and exhibits high catalytic activity toward the hydrosilylation of carbonyl compounds and the reductive silylation of dinitrogen.
Hydrosilylation of ketone and imine over poly-N-heterocyclic carbene particles
Tan, Meixuan,Zhang, Yugen,Ying, Jackie Y.
experimental part, p. 1390 - 1394 (2009/12/22)
N-Heterocyclic carbene (NHC)-catalyzed ketone/imine hydrosilylation, silane alcohol condensation and asymmetric ketone hydrosilylation reactions were demonstrated for the first time over solid, main-chain poly-NHC particles. The stable and robust poly-NHC
