24748-71-8Relevant articles and documents
Modified method of synthesis of N-substituted dithioesters of amino acids and peptides in the Pinner reaction
Neugebauer, Witold,Pinet, Eric,Kim, Munsok,Carey, Paul R.
, p. 341 - 343 (2007/10/03)
An improved method for the synthesis of dithioesters of amino acids and peptides has been developed. The syntheses have been carried out from the nitriles. The addition of thiol to the nitrile derivative in the Pinner step of dithioester synthesis was activated with hydrogen fluoride. A few examples of dithioester synthesis using liquid HF are described. Some novel dithioesters, which are model compounds for resonance Raman spectroscopic studies of dithioacylpapain intermediates, are described. An improved method for the synthesis of dithioesters of amino acids and peptides has been developed. The syntheses have been carried out from the nitriles. The addition of thiol to the nitrile derivative in the Pinner step of dithioester synthesis was activated with hydrogen fluoride. A few examples of dithioester synthesis using liquid HF are described. Some novel dithioesters, which are model compounds for resonance Raman spectroscopic studies of dithioacylpapain intermediates, are described.
Resonance Raman spectroscopic evidence for an intramolecular interaction involving th amide and dithioester groups of N-acyl glycine ethyl dithioesters
Storer, A. C.,Ozaki, Y.,Carey, P. R.
, p. 199 - 209 (2007/10/02)
The synthesis and resonance Raman spectra of several new N-acyl glycine etyl dithioesters RC(=O)NHCH2C(=S)SR are reported.The resonance Raman spectra of these compounds contain at least two peaks in the "C=S stretching region" between 1050 and 1200 cmsup
