24892-81-7

Basic information

• Product Name: 1-(1-(2-CHLOROPHENYL)VINYL)BENZENE
• Synonyms: 1-(1-(2-CHLOROPHENYL)VINYL)BENZENE;1-CHLORO-2-(1-PHENYL-VINYL)-BENZENE
• CAS NO: 24892-81-7
• Molecular Formula: C₁₄H₁₁Cl
• Molecular Weight: 214.69
• Mol File: 24892-81-7.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 311.7 °C at 760 mmHg
• Flash Point: 134.6 °C
• Appearance: /
• Density: 1.107 g/cm³
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 1-(1-(2-CHLOROPHENYL)VINYL)BENZENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(1-(2-CHLOROPHENYL)VINYL)BENZENE(24892-81-7)
• EPA Substance Registry System: 1-(1-(2-CHLOROPHENYL)VINYL)BENZENE(24892-81-7)

Safety Data

• Hazardous Substances Data: 24892-81-7(Hazardous Substances Data)

Usage

General Description

1-(1-(2-chlorophenyl)vinyl)benzene, also known as 1-(2-chlorostyryl)benzene, is a chemical compound that belongs to the family of aromatic hydrocarbons. It is a white to pale yellow crystalline solid with a molecular formula of C14H11Cl. 1-(1-(2-CHLOROPHENYL)VINYL)BENZENE is used in the production of various organic chemicals and polymers. It is also a starting material for the synthesis of pharmaceuticals and agrochemicals. 1-(1-(2-chlorophenyl)vinyl)benzene is known to be flammable and should be handled with caution to avoid any potential hazards.

Upstream product

• 917-64-6 methyl magnesium iodide 
• 5162-03-8 (2-chlorophenyl)(phenyl)methanone 
• 119-61-9 benzophenone 
• 1357011-76-7 [Y(N(SiMe₃)2)2I(OCPh₂CH₂PPh₃)] 
• 536-74-3 phenylacetylene 
• 108-90-7 chlorobenzene 
• 3752-25-8 o-chlorocinnamic acid 
• 71-43-2 benzene 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 108-86-1 bromobenzene 
• 2039-87-4 2-chlorostyrene 

Downstream Products

• 76690-79-4 1-(2-chloro-phenyl)-1-phenyl-ethane 
• 54766-44-8 2-o-Chlorphenyl-2-phenylvinyliodid 
• 1443780-53-7 4-(2-chlorophenyl)-4-phenylbutan-2-one 
• 5162-03-8 (2-chlorophenyl)(phenyl)methanone 
• 806-58-6 1,2,4-triphenylnaphthalene 

Relevant articles and documents

Photoinduced Hydroarylation and Cyclization of Alkenes with Luminescent Platinum(II) Complexes

Photoinduced hydroarylation of alkenes is an appealing synthetic strategy for arene functionalization. Herein, we demonstrated that aryl radicals generated from electron-deficient aryl chlorides/bromides could be trapped by an array of terminal/internal aryl alkenes in the presence of [Pt(O^N^C^N)] under visible-light (410 nm) irradiation, affording anti-Markovnikov hydroarylated compounds in up to 95 % yield. Besides, a protocol for [Pt(O^N^C^N)]-catalyzed intramolecular photocyclization of acrylanilides to give structurally diverse 3,4-dihydroquinolinones has been developed.

Cu/Ni-Catalyzed Cyanomethylation of Alkenes with Acetonitrile for the Synthesis of β,γ-Unsaturated Nitriles

We have developed a protocol for the Cu/Ni-catalyzed cyanomethylation of alkenes with acetonitrile for the synthesis of β,γ-unsaturated nitriles. This is the first example of a direct coupling of the alkene sp2 C - H bond and the acetonitrile sp3 C - H bond for the preparation of β,γ-unsaturated nitriles. Acetonitrile, an inexpensive and stable solvent, is demonstrated to be a useful cyanomethyl source. The combination of copper and nickel catalysts resulted in a high reaction efficiency.

Synthesis of Trifluoromethylated Tetrasubstituted Allenes via Palladium-Catalyzed Carbene Transfer Reaction

Herein, we report on the palladium-catalyzed synthesis of trifluoromethylated, tetrasubstituted allenes from vinyl bromides and trifluoromethylated diazoalkanes in good to excellent yield. This reaction proceeds via oxidative addition of a Pd(0) complex w