250722-00-0

Basic information

• Product Name: tetrabutylammonium perfluoro-2-methylcyclohex-1-enolate
• CAS NO: 250722-00-0
• Molecular Weight: 551.527
• Mol File: 250722-00-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tetrabutylammonium perfluoro-2-methylcyclohex-1-enolate(CAS DataBase Reference)
• NIST Chemistry Reference: tetrabutylammonium perfluoro-2-methylcyclohex-1-enolate(250722-00-0)
• EPA Substance Registry System: tetrabutylammonium perfluoro-2-methylcyclohex-1-enolate(250722-00-0)

Safety Data

• Hazardous Substances Data: 250722-00-0(Hazardous Substances Data)

Upstream product

• 937704-62-6 C₈F₁₄O₃S 
• 311-28-4 tetra-(n-butyl)ammonium iodide 
• 355-02-2 perfluoro(methylcyclohexane) 
• 85577-98-6 1-methoxy-2-trifluoromethyloctafluorocyclohex-1-ene 

Downstream Products

• 937704-63-7 C₇ClF₉O 
• 937704-62-6 C₈F₁₄O₃S 
• 85577-98-6 1-methoxy-2-trifluoromethyloctafluorocyclohex-1-ene 

Relevant articles and documents

Functionalization of saturated fluorocarbons with and without light

Photochemical transformation of saturated fluorocarbons into tetrabutylammonium enolates has been improved, and a method employing ketyls as reductants has been developed that accomplishes the same chemistry without light. Enolates have been isolated as enol methyl ethers, from which they can be efficiently regenerated with tetrabutylammonium iodide. In other cases, enolates have been isolated as the corresponding ketone or stable enol. Fluorocarbon LUMO energies correlate with their reactivity and serve as a guide to the choice of ketyl. Use of this chemistry for fluoropolymer surface modification is discussed.