85577-98-6

Basic information

• Product Name: 1-methoxy-2-trifluoromethyloctafluorocyclohex-1-ene
• Synonyms: 1-methoxy-2-trifluoromethyloctafluorocyclohex-1-ene
• CAS NO: 85577-98-6
• Molecular Weight: 324.094
• Mol File: 85577-98-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-methoxy-2-trifluoromethyloctafluorocyclohex-1-ene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methoxy-2-trifluoromethyloctafluorocyclohex-1-ene(85577-98-6)
• EPA Substance Registry System: 1-methoxy-2-trifluoromethyloctafluorocyclohex-1-ene(85577-98-6)

Safety Data

• Hazardous Substances Data: 85577-98-6(Hazardous Substances Data)

Upstream product

• 250722-00-0 tetrabutylammonium perfluoro-2-methylcyclohex-1-enolate 
• 77-78-1 dimethyl sulfate 
• 333-27-7 methyl trifluoromethanesulfonate 
• 67-56-1 methanol 
• 432-16-6 1-trifluoro-methylnonafluorocyclohex-1-ene 

Downstream Products

• 250722-00-0 tetrabutylammonium perfluoro-2-methylcyclohex-1-enolate 
• 85578-01-4 trans-1-Methoxy-2-trifluoromethyldecafluorocyclohexane 
• 85578-01-4 cis-1-Methoxy-2-trifluoromethyldecafluorocyclohexane 
• 376-73-8 hexafluoroglutaric acid 

Relevant articles and documents

Functionalization of saturated fluorocarbons with and without light

Photochemical transformation of saturated fluorocarbons into tetrabutylammonium enolates has been improved, and a method employing ketyls as reductants has been developed that accomplishes the same chemistry without light. Enolates have been isolated as enol methyl ethers, from which they can be efficiently regenerated with tetrabutylammonium iodide. In other cases, enolates have been isolated as the corresponding ketone or stable enol. Fluorocarbon LUMO energies correlate with their reactivity and serve as a guide to the choice of ketyl. Use of this chemistry for fluoropolymer surface modification is discussed.

POLYFLUOROCYCLOALKENES. PART XVI . SOME ADDITION REACTIONS OF 1-TRIFLUOROMETHYLNONAFLUOROCYCLOHEX-1-ENE

Reactions with alcohols and base repleaced the vinylic fluorine of 1-trifluoromethylnonafluorocyclohex-1-ene (I) by methoxy and ethoxy groups.Fluorination with cobaltic fluoride gave, from the former, a number of saturated polyfluoro-ethers.Oxidation of the alkoxy-cycloalkenes gave hexafluoroglutaric acid.Cycloalkene I gave with ammonia an imino-enamine, which was hydrolysed by dilute acid to a keto-enamine.I was defluorinated by heated iron to octafluorotoluene.