2508-23-8Relevant articles and documents
A Direct Aromatic Methylsulfanylation of N-Aryl-N-methoxyacetamides with an Aluminium Chloride-Dimethyl Sulfide System
Matsumoto, Kazuhiro,Kato, Miyako,Sakamoto, Takeshi,Kikugawa, Yasuo
, p. 34 - 35 (2007/10/03)
Treatment of N-aryl-N-methoxyacetamides, which bear a strong electron-donating group on the aryl ring, with an AlCl3-Me2S system results in heterocyclic cleavage of the nitrogen-oxygen bond and introduction of a methylsulfanyl group at the ortho or para position of the aryl ring.
The Solvolysis of N-Acetoxy-2-acetylaminofluorene and N-Acetoxy-4-acetylaminobiphenyl: Delicate Balance between Nitrenium Ion Formation and Hydrolysis
Underwood, Graham R.,Kirsch, Robert B.
, p. 136 - 138 (2007/10/02)
The solvolysis of N-acetoxy-2-acetylaminofluorene in aqueous acetone at neutral pH proceeds exclusively with nitrenium ion formation while under the same conditions, the 4-aminobiphenyl analogue undergoes exclusive acyl-oxygen scission.