25333-24-8

Basic information

• Product Name: METHYL 3-BENZOYLPROPIONATE
• Synonyms: TIMTEC-BB SBB008046;3-BENZOYLPROPIONIC ACID METHYL ESTER;4-OXO-4-PHENYLBUTYRIC ACID METHYL ESTER;METHYL 3-BENZOYLPROPIONATE;METHYL 4-OXO-4-PHENYLBUTYRATE;Methyl 3-benzoylpropanoate;Methyl 4-oxo-4-phenylbutanoate;Propionic acid, 3-benzoyl-, methyl ester
• CAS NO: 25333-24-8
• Molecular Formula: C₁₁H₁₂O₃
• Molecular Weight: 192.21
• Product Categories: Aromatic Propionic Acids
• Mol File: 25333-24-8.mol
• Article Data: 81

Chemical Properties

• Boiling Point: 172-174 °C (10 mmHg)
• Flash Point: 172-174°C/10mm
• Appearance: /
• Density: 1.14
• Vapor Pressure: 0.000707mmHg at 25°C
• Refractive Index: 1.523-1.525
• Solubility: Soluble in Chloroform.
• BRN: 2211627
• CAS DataBase Reference: METHYL 3-BENZOYLPROPIONATE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL 3-BENZOYLPROPIONATE(25333-24-8)
• EPA Substance Registry System: METHYL 3-BENZOYLPROPIONATE(25333-24-8)

Safety Data

• Safety Statements: 24/25
• Hazardous Substances Data: 25333-24-8(Hazardous Substances Data)

Usage

Description

METHYL 3-BENZOYLPROPIONATE, also known as Methyl 3-(phenylcarbonyl)propanoate, is an organic compound that serves as a chemical and organic intermediate. It is a clear colorless to yellow liquid with unique chemical properties that make it suitable for various applications across different industries.

Uses

Used in Chemical Industry:
METHYL 3-BENZOYLPROPIONATE is used as a chemical intermediate for the synthesis of various compounds and materials. Its chemical structure allows it to be a versatile building block in the creation of pharmaceuticals, agrochemicals, and other specialty chemicals.
Used in Pharmaceutical Industry:
METHYL 3-BENZOYLPROPIONATE is used as an organic intermediate in the development of new drugs and pharmaceutical compounds. Its unique properties enable it to be a key component in the synthesis of novel therapeutic agents, potentially contributing to the advancement of medical treatments.
Used in Agrochemical Industry:
METHYL 3-BENZOYLPROPIONATE is used as an organic intermediate in the formulation of agrochemicals, such as pesticides and herbicides. Its role in these products helps to improve the efficiency and effectiveness of these chemicals in agricultural applications.
Used in Specialty Chemicals Industry:
METHYL 3-BENZOYLPROPIONATE is used as a chemical intermediate in the production of specialty chemicals, which are tailored to meet specific requirements in various industries, such as cosmetics, coatings, and plastics. Its unique properties make it a valuable component in the development of these specialized products.

InChI:InChI=1/C11H12O3/c1-14-11(13)8-7-10(12)9-5-3-2-4-6-9/h2-6H,7-8H2,1H3

Upstream product

• 41158-32-1 methyl 4-oxo-4-phenylbut-2-ynoate 
• 67-56-1 methanol 
• 2051-95-8 succinylbenzene 
• 2674-04-6 diphenyl cadmium 
• 1490-25-1 succinic acid monomethylester chloride 
• 186581-53-3 diazomethane 
• 2415-80-7 1,1-dichloro-2-phenylcyclopropane 
• 124-38-9 carbon dioxide 
• 124-41-4 sodium methylate 
• 74-85-1 ethene 
• 201230-82-2 carbon monoxide 
• 56346-03-3 C₁₁H₁₄LiNOSi 
• 22049-87-2 rac-4-nitro-4-phenyl-butyric acid methyl ester 
• 33553-90-1 4-hydroxy-4-phenyl-but-2-ynoic acid methyl ester 

Downstream Products

• 24459-27-6 2-methyl-5-phenylhexane-2,5-diol 
• 53774-19-9 4-phenyl-3-pentenoic acid 
• 14274-07-8 methyl 3-benzoylacrylate 
• 16115-36-9 4-(2-oxo-5-phenyl-1,2-dihydro-pyrrol-3-ylidene)-4-phenyl-butyric acid methyl ester 
• 134953-19-8 (E)-4-phenylhex-3-enoic acid 
• 63469-15-8 1,1,4,4-tetraphenyl-1,4-butanediol 
• 4850-50-4 1-phenyl-butane-1,4-diol 
• 2051-95-8 succinylbenzene 
• 26551-48-4 Methyl 3-bromo-4-keto-4-phenylbutanoate 
• 860361-30-4 1-phenethyl-5-phenyl-pyrrolidin-2-one 
• 39755-03-8 4-hydroxy-1-phenyl-butan-1-one 
• 939-52-6 4-chloro-1-phenylbutan-1-one 
• 103632-91-3 2-[2-(methoxycarbonyl)ethyl]-2-phenyl-1,3-dioxolane 
• 67545-37-3 4-hydroxy-4-phenyl-hexanoic acid 

Relevant articles and documents

3,6-bis(triphenylphosphonium)cyclohexene peroxodisulfate: A highly efficient oxidant for the selective oxidation of benzylic alcohols

The synthesis of 3,6-bis(triphenylphosphonium)cyclohexene peroxodisulfate and its application for the selective oxidation of benzylic alcohols is reported.

LIGHT INDUCED CATALYTIC C-H OXYGENATION OF ALKANES

A method of oxygenating a benzylic C-H bond is provided. The method comprises light induced activation of an initiator and subsequent reaction with oxygen, resulting in the formation of free radicals. Subsequently, free radicals catalyze the reaction of the benzylic C-H bond with oxygen, thereby forming an oxygenated compound.

Metal-free reduction of unsaturated carbonyls, quinones, and pyridinium salts with tetrahydroxydiboron/water

A series of unsaturated carbonyls, quinones, and pyridinium salts have been effectively reduced to the corresponding saturated carbonyls, dihydroxybenzenes, and hydropyridines in moderate to high yields with tetrahydroxydiboron/water as a mild, convenient, and metal-free reduction system. Deuterium-labeling experiments have revealed this protocol to be an exclusive transfer hydrogenation process from water. This journal is

Visible-Spectrum Solar-Light-Mediated Benzylic C-H Oxygenation Using 9,10-Dibromoanthracene As an Initiator

We report a visible-light-mediated benzylic C-H oxygenation reaction. The reaction is initiated by solar light or the blue LED activation of 9,10-dibromoanthracene in a reaction with oxygen and takes place at ambient temperature and air pressure. Secondary benzylic positions are oxygenated to ketones, while tertiary benzylic carbons are oxygenated to give hydroperoxides. Notably, cumene hydroperoxide is produced in a higher yield and at milder conditions than the currently employed industrial conditions.