56346-03-3

Basic information

• Product Name: C₁₁H₁₄LiNOSi
• Synonyms: C₁₁H₁₄LiNOSi
• CAS NO: 56346-03-3
• Molecular Weight: 211.265
• Mol File: 56346-03-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₁H₁₄LiNOSi(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₁H₁₄LiNOSi(56346-03-3)
• EPA Substance Registry System: C₁₁H₁₄LiNOSi(56346-03-3)

Safety Data

• Hazardous Substances Data: 56346-03-3(Hazardous Substances Data)

Upstream product

• 25438-37-3 phenyl(trimethylsiloxy)acetonitrile 

Downstream Products

• 25333-24-8 3-benzoylpropionic acid methyl ester 
• 73593-53-0 5,5-dimethyl-3-benzoyl-2-cyclohexen-1-one 
• 582299-16-9 2-cyclopentyl-2-hydroxy-1-phenylethan-1-one 
• 582299-15-8 2-cyclobutyl-2-hydroxy-1-phenylethan-1-one 
• 73593-52-9 8a-Benzoyl-3,4,4a,5,6,7,8,8a-octahydro-2(1H)-naphthalinon 
• 73593-57-4 4-Oxo-2,3,4-triphenyl-2,3-bis(trimethylsiloxy)butannitril 
• 73593-63-2 α-<5,5-Dimethyl-3-(trimethylsiloxy)-3-cyclohexen-1-yl>-α-(trimethylsiloxy)benzolacetonitril 
• 73593-62-1 α-(Trimethylsiloxy)-α-<3-(trimethylsiloxy)-3-cyclohexen-1-yl>benzolacetonitril 
• 73593-61-0 3,3-Dimethyl-2-phenyl-2,5-bis(trimethylsiloxy)-5-hexennitril 
• 73593-49-4 5-Benzoyl-3,3-dimethyl-1-cyclohexanon 
• 39121-67-0 2,2-dimethyl-1-phenylpentane-1,4-dione 
• 58753-28-9 3-benzoylcyclohexan-1-one 
• 25234-76-8 1,2-diphenyl-1,4-pentanedione 
• 343933-16-4 methanesulfonic acid 1-cyclohexyl-2-oxo-2-phenyl-ethyl ester 

Relevant articles and documents

Trimethylsilyl Cyanide - A Reagent for Umpolung, III: Nucleophilic Acylation of α,β-Unsaturated Carbonyl Compounds with directed 1,2-/1,4-Additions by Solvent Effects

The anion 7 of O-(trimethylsilyl)cyanohydrine 6, derived from benzaldehyde, attacks numerous α-enones in ether exclusively by 1,4-addition, even if C-3 is alkyl-substituted.In THF and DME the 1,2-adduct is formed predominantly; on addition of HMPT or 12-c