25478-60-8

Basic information

• Product Name: dicarbonyldichloroplatinum
• Synonyms: dicarbonyldichloroplatinum;Dicarbonyl platinous dichloride
• CAS NO: 25478-60-8
• Molecular Formula: C₂Cl₂O₂Pt
• Molecular Weight: 326.03596
• EINECS: 247-018-7
• Mol File: 25478-60-8.mol
• Article Data: 10

Chemical Properties

• Appearance: /
• CAS DataBase Reference: dicarbonyldichloroplatinum(CAS DataBase Reference)
• NIST Chemistry Reference: dicarbonyldichloroplatinum(25478-60-8)
• EPA Substance Registry System: dicarbonyldichloroplatinum(25478-60-8)

Safety Data

• Hazardous Substances Data: 25478-60-8(Hazardous Substances Data)

Upstream product

• 106863-38-1 [PtI₂(CO)2] 
• 7791-25-5 sulfuryl dichloride 
• 201230-82-2 carbon monoxide 
• 15617-14-8 cis-dichlorobis(propiononitrile)platinum(II) 
• 107-12-0 propiononitrile 
• 7719-09-7 thionyl chloride 
• 10025-65-7 platinum(II) chloride 
• 7440-06-4 platinum 
• 79-37-8 oxalyl dichloride 
• 13454-96-1 platinum(IV) chloride 
• 25478-60-8 trans-PtCl₂(CO)2 
• 7782-50-5 chlorine 
• 133698-96-1 cis-dichloro(η2-cyclohexene)carbonyl-platinum(II) 
• 865088-04-6 cis-[PtCl₂(CO)(1-octene)] 

Downstream Products

• 12080-32-9 dichloro( 1,5-cyclooctadiene)platinum(ll) 
• 7647-01-0 hydrogenchloride 
• 124-38-9 carbon dioxide 
• 13965-02-1 cis-dichlorobis(triethylphosphine)platinum(II) 
• 12152-26-0 dichloro-(η**(4)-bicyclo[2.2.1]hepta-2,5-diene)platinum(II) 
• 7440-06-4 platinum 
• 126136-26-3 Pt{C(Ph)=C(H)C(=O)Me}(CO)Cl 
• 116746-89-5 [((C₆H₅)3P)2N]⁽¹⁺⁾*[PtCl₃(CO)]^(1-)=[((C₆H₅)3P)2N](PtCl₃(CO)) 
• 95662-41-2 [Pt₂(C₄(CH₃)2(C₆H₅)2)2Cl₃]⁽¹⁺⁾*[Pt(CO)Cl₃]^(1-)=[Pt₂(C₄(CH₃)2(C₆H₅)2)2Cl₃][Pt(CO)Cl₃] 
• 95686-58-1 [Pt₂(C₄(CH₃)2(C₆H₅)2)2Cl₃]⁽¹⁺⁾*[Pt(CO)Cl₃]^(1-)=[Pt₂(C₄(CH₃)2(C₆H₅)2)2Cl₃][Pt(CO)Cl₃] 
• 66219-46-3 [Pt(C(CO₂Et)C(Cl)COO)(CO)] 
• 75-44-5 phosgene 
• 25478-60-8 cis-dicarbonyldichloroplatinum(II) 

Relevant articles and documents

Dissociation of the FEBID precursor: Cis-Pt(CO)2Cl2 driven by low-energy electrons

In this study, we present experimental and theoretical results on dissociative electron attachment and dissociative ionisation for the potential FEBID precursor cis-Pt(CO)2Cl2. UHV surface studies have shown that high purity platinum

A kinetic study of the competition between carbon monoxide and alkenes in chloro complexes of platinum(II)

Alkenes (cyclohexene; 1-octene) react with cis-PtCl2 (CO) 2, leading to cis-PtCl2(CO)(alkene) (1a, alkene = cyclohexene; 1b, alkene = 1-octene). The substitution kinetics to 1a and 1b in 1, 2-dichloroethane in the temperature range 273-308 K have the following second-order rate constants at 298 K, respectively: cyclohexene, (0.94 ± 0.07) × 10-3 M-1 s-1 1-octene, (2.33 ± 0.05) × 10-2 M-1 s-1. The activation parameters are ΔH* = 37 ± 4 kJ mol-1, ΔS* = -180 ± 10 J K-1 mol-1 for the reaction affording la and ΔH* = 36.5 ± 0.7 kJ mol -1, ΔS* = -154 ± 2 J K-1 mol -1 for the reaction to 1b. The large negative values of the activation entropies are consistent with an associative mechanism. The reverse reactions proceed with a similar rate constant.

New routes to the synthesis of chloro-carbonyls of palladium(II) and platinum(II)

[Pt(CO)x]n (x～2), the already described species obtained by the reaction of platinum(0) olefin complexes with carbon monoxide, reacts promptly at room temperature with SO2Cl2 under CO affording cis-PtCl2/s