25891-89-8Relevant articles and documents
Pallado-catalysed P-arylations and P-vinylation of 2-hydrogeno-2-oxo-1,4,2- oxazaphosphinanes
Pirat, Jean-Luc,Monbrun, Jér?me,Virieux, David,Cristau, Henri-Jean
, p. 7029 - 7036 (2005)
A simple and effective preparation of 2-aryl- (or 2-vinyl)-1,4,2- oxazaphosphinanes, phosphorus analogues of aryl-morpholinols has been developed, involving palladium catalysed coupling of aryl (or vinyl)-halides with 2-H-1,4,2-oxazaphosphinane in presenc
A recyclable chiral auxiliary for the asymmetric syntheses of α-aminonitriles and α-aminophosphinic derivatives
Rossi, Jean-Christophe,Marull, Marc,Larcher, Nicolas,Taillades, Jacques,Pascal, Robert,van der Lee, Arie,Gerbier, Phillipe
, p. 876 - 883 (2008/09/21)
Optically active α-aminonitriles and α-aminophosphinic derivatives have been prepared in high yield and high ee using an easy route by extending our previously developed method involving the following sequence: (i) stereoselective Strecker condensation of
Studies on Organophosphorus Compounds XXVIII. An Improved Synthetic Route to 1-Amino-Substituted Benzyl Phosphonic and -Phosphinic Acids
Yuan, Chengye,Qi, Youmao
, p. 472 - 474 (2007/10/02)
An improved method for the synthesis of 1-aminosubstituted benzyl phosphonic and -phosphinic acids under mild conditions is described.It consists of the reaction of diphenoxy chlorophosphine (1) or dichlorophenylphosphine (6) with substituted benzaldehyde