262279-40-3

Basic information

• Product Name: (3S,8R,9S)-(E)-tert-butyl 3-(tert-butyldiphenylsiloxy)-7-oxo-8-methyl-9-methoxy-9-(2-hydroxymethyl-2,4'-trisoxazole-4'-yl)-non-5-enoate
• Synonyms: (3S,8R,9S)-(E)-tert-butyl 3-(tert-butyldiphenylsiloxy)-7-oxo-8-methyl-9-methoxy-9-(2-hydroxymethyl-2,4'-trisoxazole-4'-yl)-non-5-enoate
• CAS NO: 262279-40-3
• Molecular Weight: 755.94
• Mol File: 262279-40-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (3S,8R,9S)-(E)-tert-butyl 3-(tert-butyldiphenylsiloxy)-7-oxo-8-methyl-9-methoxy-9-(2-hydroxymethyl-2,4'-trisoxazole-4'-yl)-non-5-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,8R,9S)-(E)-tert-butyl 3-(tert-butyldiphenylsiloxy)-7-oxo-8-methyl-9-methoxy-9-(2-hydroxymethyl-2,4'-trisoxazole-4'-yl)-non-5-enoate(262279-40-3)
• EPA Substance Registry System: (3S,8R,9S)-(E)-tert-butyl 3-(tert-butyldiphenylsiloxy)-7-oxo-8-methyl-9-methoxy-9-(2-hydroxymethyl-2,4'-trisoxazole-4'-yl)-non-5-enoate(262279-40-3)

Safety Data

• Hazardous Substances Data: 262279-40-3(Hazardous Substances Data)

Upstream product

• 262279-33-4 (3S,8R,9S)-(E)-tert-butyl 3-(tert-butyldiphenylsiloxy)-7-oxo-8-methyl-9-methoxy-9-(tert-butyldiphenylsiloxymethyl-2,4'-trisoxazole-4'-yl)-non-5-enoate 
• 14036-55-6 t-butyl vinylacetate 
• 108100-50-1 (+/-)-tert-butyl 3,4-epoxybutanoate 
• 194232-63-8 2''-(tert-Butyl-diphenyl-silanyloxymethyl)-[2,4';2',4'']teroxazole-4-carbaldehyde 
• 262279-31-2 (5S,6S)-(E)-methyl 6-methoxy-5-methyl-6-(2-tert-butyldiphenylsiloxymethyl-2,4'-trisoxazole-4'-yl)-hex-3-enoate 
• 262279-29-8 (E)-(S)-3-Hydroxy-6-iodo-hex-5-enoic acid tert-butyl ester 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 313696-78-5 (2R,3S,4R,5S)-2-methylcarbonylmethyl-3-phenyldimethylsilyl-4-methyl-5-(2-tert-butyldiphenylsiloxymethyl-2,4'-trisoxazole-4'-yl)tetrahydrofuran 
• 313696-94-5 (2R,3S)-3-[2''-(tert-Butyl-diphenyl-silanyloxymethyl)-[2,4';2',4'']teroxazol-4-yl]-3-methoxy-2-methyl-propionyl chloride 
• 262279-32-3 (3S,8S,9S)-(E)-tert-butyl 3-(tert-butyldiphenylsiloxy)-7-hydroxy-8-methyl-9-methoxy-9-(tert-butyldiphenylsiloxymethyl-2,4'-trisoxazole-4'-yl)-non-5-enoate 
• 262279-30-1 (5S,6S)-(E)-methyl 6-hydroxyl-5-methyl-6-(2-tert-butyldiphenylsiloxymethyl-2,4'-trisoxazole-4'-yl)-hex-3-enoate 
• 262279-27-6 (5R,6S)-3-methoxy-2-methyl-3-(2-tert-butyldiphenylsiloxymethyl-2,4'-trioxazole-4'-yl)-propanal 
• 262279-26-5 (S)-(E)-tert-butyl 3-(tert-butyldiphenylsilyl)oxy-6-iodo-hex-5-enoate 
• 108100-50-1 (R)-tert-butyl 3,4-epoxybutanoate 

Downstream Products

• 262279-24-3 (3S,8R,9S)-(E)-3-(tert-butyldiphenylsiloxy)-7-oxo-8-methyl-9-methoxy-9-(2-bromomethyl-2,4'-trisoxazole-4'-yl)-non-5-enoic acid 
• 262279-37-8 C₆₆H₈₉N₃O₁₅Si 
• 262279-42-5 9-{2''-[14-acetoxy-16-(5,5-dimethyl-[1,3]dioxan-2-yl)-6-hydroxy-4,8-dimethoxy-5,9,13,15-tetramethyl-12-oxo-hexadec-1-enyl]-[2,4';2',4'']teroxazol-4-yl}-3-(tert-butyl-diphenyl-silanyloxy)-9-methoxy-8-methyl-7-oxo-non-5-enoic acid 
• 262279-36-7 C₇₂H₁₀₅N₃O₁₆Si₂ 
• 262279-38-9 C₆₃H₈₂N₄O₁₄Si 
• 262279-41-4 (3S,8R,9S)-(E)-tert-butyl 3-(tert-butyldiphenylsiloxy)-7-oxo-8-methyl-9-methoxy-9-(2-bromomethyl-2,4'-trisoxazole-4'-yl)-non-5-enoate 

Relevant articles and documents

Total synthesis of the actin-depolymerizing agent (-)-mycalolide A: Application of chiral silane-based bond construction methodology

A highly convergent asymmetric synthesis of the actin-depolymerizing agent (-)-mycalolide A has been achieved through the assembly and union of the C1-C19 trisoxazole fragment 2 and the C20-C35 aliphatic fragment 3, respectively. The C1-C19 fragment 2 was