262849-39-8

Basic information

• Product Name: (2S)-1-acetoxy-2-methyl-3-p-methoxyphenylpropane
• Synonyms: (2S)-1-acetoxy-2-methyl-3-p-methoxyphenylpropane
• CAS NO: 262849-39-8
• Molecular Weight: 222.284
• Mol File: 262849-39-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2S)-1-acetoxy-2-methyl-3-p-methoxyphenylpropane(CAS DataBase Reference)
• NIST Chemistry Reference: (2S)-1-acetoxy-2-methyl-3-p-methoxyphenylpropane(262849-39-8)
• EPA Substance Registry System: (2S)-1-acetoxy-2-methyl-3-p-methoxyphenylpropane(262849-39-8)

Safety Data

• Hazardous Substances Data: 262849-39-8(Hazardous Substances Data)

Upstream product

• 108-05-4 vinyl acetate 
• 64506-21-4 (+/-)-2-methyl-3-(p-methoxyphenyl)propanol 
• 126356-04-5 (E)-methyl 2-methyl-3-(p-methoxyphenyl)prop-2-enoate 
• 17226-85-6 α,β-syn-methyl 3-hydroxy-2-methyl-3-(p-methoxyphenyl)propionate 
• 17226-85-6 α,β-anti-methyl 3-hydroxy-2-methyl-3-(p-methoxyphenyl)propionate 
• 91970-30-8 (E)-3-(4-Methoxyphenyl)-2-methylprop-2-en-1-ol 
• 92656-06-9 (2R,3R)-(1,3)-diacetoxy-2-methyl-3-p-methoxyphenylpropane 
• 262849-41-2 Acetic acid (2R,3R)-3-hydroxy-3-(4-methoxy-phenyl)-2-methyl-propyl ester 

Downstream Products

• 185681-32-7 (S)-1-bromo-2-methyl-3-(p-methoxyphenyl)propanol 
• 185681-33-8 (2S)-2-methyl-3-(p-methoxyphenyl)-1-phenylsulfonylpropane 
• 79253-39-7 (S)-(-)-3-(4-methoxyphenyl)-2-methylpropan-1-ol 

Relevant articles and documents

Chemoenzymatic synthesis of (+)-α-polypodatetraene and methyl (5R,10R,13R)-labda-8-en-15-oate

The reported enzymatic resolution products {acetate of (1S,4aS,8aS)-1,2,3, 4,4a,5,6,7,8,8a-decahydro-5,5,8a-trimethyl-2-oxo-trans-naphthalene-1-methanol-2- ethylene acetal} (8aS)-5 (>99% ee)] and [(1R,4aR,8aR)-1,2,3,4,4a,5,6,7,8,8a- decahydro-5,5,8a-trimethyl-2-oxo-trans-naphthalene-1-methanol-2-ethylene acetal (8aR)-4 (98% ee) were converted to (+)-α-polypodatetraene (1) and methyl (5R,10R,13R)-labda-8-en-15-oate (2), respectively. For the synthesis of (5R,10R,13R)-2, chiral isoprene congener (3S)-26 corresponding to the right part of 2 was synthesized based on the lipase-assisted resolution of (±)-2-methyl-3- (p-methoxyphenyl)propanol (17).