26620-11-1

Basic information

• Product Name: Benzene, [(2-chloroethenyl)thio]-, (E)-
• CAS NO: 26620-11-1
• Molecular Formula: C8H7ClS
• Molecular Weight: 170.663
• Mol File: 26620-11-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, [(2-chloroethenyl)thio]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(2-chloroethenyl)thio]-, (E)-(26620-11-1)
• EPA Substance Registry System: Benzene, [(2-chloroethenyl)thio]-, (E)-(26620-11-1)

Safety Data

• Hazardous Substances Data: 26620-11-1(Hazardous Substances Data)

Upstream product

• 931-59-9 benzenesulfenyl chloride 
• 74-86-2 acetylene 
• 60785-23-1 2,2-dichloroethylthiobenzene 
• 108-98-5 thiophenol 
• 86240-69-9 (1,2-Dichloro-ethylsulfanyl)-benzene 
• 540-59-0 1,2-Dichloroethylene 
• 79-00-5 1,1,2-trichloroethane 
• 156-60-5 trans-1,2-dichloroethylene 

Downstream Products

• 161944-19-0 Trimethyl-((E)-4-phenylsulfanyl-but-3-en-1-ynyl)-silane 
• 1283118-75-1 C₂₀H₂₆O₂S 
• 1283118-76-2 C₂₈H₄₀N₂O₆S 
• 185323-23-3 [Rh(C₄H₇N₂O₂)2(PPh₃)(trans-CHCHSC₆H₅)] 
• 99904-09-3 N-(2ξ-benzenesulfonyl-vinyl)-hydroxylamine 
• 37530-86-2 1-phenylsulfonyl-2-(phenylthio)ethene 
• 963-16-6 (E)-1,2-bis(phenylsulfonyl)ethylene 
• 92765-72-5 (2ξ-benzenesulfonyl-vinyl)-methyl-amine 
• 108344-86-1 (Z)-1-(phenylsulfonyl)-3,3-dimethylbut-1-ene 
• 68969-27-7 (E)-1-(phenylsulfonyl)-3,3-dimethylbut-1-ene 
• 1071096-35-9 2-((1E,3E)-4-Phenylsulfanyl-buta-1,3-dienyl)-thiophene 
• 161944-20-3 (1E,3E)-1-bromo-4-phenylthio-1,3-butadiene 
• 35347-66-1 (E)-1-phenylthio-1-buten-3-yne 
• 18893-63-5 (E)-1,2-bis(phenylsulfanyl)ethylene 

Relevant articles and documents

Novel stereoselective phase transfer catalytic synthesis and some applications of (E)-2-chlorovinylthioarenes and hetarenes

A novel two-step method for the preparation of (E)-2-chlorovinyl-thioarenes (or hetarenes) from thiols and 1,1,2-trichloroethane in the phase transfer catalytic systems solid K2CO3/solid KI/18-crown-6/xylene and solid KOH/18-crown-6/

HIGH-TEMPERATURE ORGANIC SYNTHESIS. XXXIX. GAS-PHASE REACTION OF THIOPHENOL WITH 1,2-DICHLOROETHENE

Thiophenol reacts with 1,2-dichloroethene (a 3:1 mixture of E and Z isomers) in the gas phase at 400-550 deg C forming phenyl β-chlorovinyl sulfide (E and Z isomers, 1:1) with an overall yield of up to 84percent.The products from its further thermal transformations are benzothiophene. 3-chlorobenzothiophene, 1,2-bis(phenylthio)ethene (a mixture of stereoisomers), and 3-phenylthiobenzothiophene