26818-05-3Relevant articles and documents
Halofunctionalization of alkenes by vanadium chloroperoxidase from: Curvularia inaequalis
Dong, Jia Jia,Fernández-Fueyo, Elena,Li, Jingbo,Guo, Zheng,Renirie, Rokus,Wever, Ron,Hollmann, Frank
supporting information, p. 6207 - 6210 (2017/07/10)
The vanadium-dependent chloroperoxidase from Curvularia inaequalis is a stable and efficient biocatalyst for the hydroxyhalogenation of a broad range of alkenes into halohydrins. Up to 1 200 000 TON with 69 s-1 TOF were observed for the biocatalyst. A bienzymatic cascade to yield epoxides as reaction products is presented.
Micellar Effects upon Alkene Bromination. 2. The Role of Alkene Hydrophobicity
Cerichelli, Giorgio,Grande, Celeste,Luchetti, Luciana,Mancini, Giovanna
, p. 3025 - 3030 (2007/10/02)
Surface polarity of cettyltrimethylammonium bromide (CTAB) aqueous micelles was checked by use of as a probe the bromination reaction of a series of 1-alkenes and a water-soluble alkene, cis-4-cyclohexene-1,2-dicarboxylic acid dimethyl ester (I).There was
A Short and Efficient Synthesis of 4,5-Disubstituted-1-pentenes
De Camp Schuda, Ann,Mazzocchi, Paul H.,Fritz, Gregory,Morgan, Tina
, p. 309 - 312 (2007/10/02)
A one step synthesis of 5-chloro-4-hydroxy-1-pentene (65percent) and 5-bromo-4-hydroxy-1-pentene (81percent) was developed.Treatment of epibromohydrin or epichlorohydrin at -73 deg C with a reagent prepared from vinylmagnesium bromide and a catalytic amount of copper(I) bromide gave the desired products. 5-Bromo-4-hydroxy-1-pentene in was cleanly converted to 4,5-epoxy-1-pentene in 99percent yield by treatment with potassium hydroxide.A number of derivatives of 5-bromo-4-hydroxy-1-pentene are described.