268737-92-4

Basic information

• Product Name: Benzoic acid (1R,5R)-5-(tert-butyl-dimethyl-silanyloxymethyl)-cyclopent-2-enyl ester
• Synonyms: Benzoic acid (1R,5R)-5-(tert-butyl-dimethyl-silanyloxymethyl)-cyclopent-2-enyl ester
• CAS NO: 268737-92-4
• Molecular Weight: 332.515
• Mol File: 268737-92-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzoic acid (1R,5R)-5-(tert-butyl-dimethyl-silanyloxymethyl)-cyclopent-2-enyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid (1R,5R)-5-(tert-butyl-dimethyl-silanyloxymethyl)-cyclopent-2-enyl ester(268737-92-4)
• EPA Substance Registry System: Benzoic acid (1R,5R)-5-(tert-butyl-dimethyl-silanyloxymethyl)-cyclopent-2-enyl ester(268737-92-4)

Safety Data

• Hazardous Substances Data: 268737-92-4(Hazardous Substances Data)

Upstream product

• 268737-89-9 (2S,3R)-2-Allyl-1-((R)-4-benzyl-2-thioxo-oxazolidin-3-yl)-3-hydroxy-pent-4-en-1-one 
• 268737-90-2 [4S,2R,3R]-(4-benzyl-2-thioxooxazolidin-3-yl)(2-hydroxycyclopent-3-enyl)methanone 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 93-97-0 benzoic acid anhydride 
• 268737-91-3 (1R,5R)-5-(tert-Butyl-dimethyl-silanyloxymethyl)-cyclopent-2-enol 
• 143395-28-2 (1R,5R)-5-hydroxymethyl-2-cyclopenten-1-ol 

Downstream Products

• 136470-78-5 abacavir 
• 136522-33-3 (1S,4R)-4-[2-amino-6-chloro-9H-purin-9-yl]-2-cyclopentene-1-methanol 
• 268737-86-6 cis-3-benzoyloxy-4-(hydroxymethyl)cyclopentene 

Relevant articles and documents

Solid-phase synthesis of carbocyclic nucleosides.

[formula: see text] An efficient solid-phase synthesis of carbocyclic nucleosides has been developed. The key step is the palladium-catalyzed coupling of a purine derivative to a resin-bound allylic benzoate. The resulting products may be further functionalized on the solid phase. Acidic cleavage affords carbocyclic nucleosides, a class of compounds with demonstrated biological activity and substantial current interest.