270588-96-0

Basic information

• Product Name: Pyridine, 2-[dimethyl[(1E)-2-phenylethenyl]silyl]-
• CAS NO: 270588-96-0
• Molecular Formula: C15H17NSi
• Molecular Weight: 239.392
• Mol File: 270588-96-0.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Pyridine, 2-[dimethyl[(1E)-2-phenylethenyl]silyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Pyridine, 2-[dimethyl[(1E)-2-phenylethenyl]silyl]-(270588-96-0)
• EPA Substance Registry System: Pyridine, 2-[dimethyl[(1E)-2-phenylethenyl]silyl]-(270588-96-0)

Safety Data

• Hazardous Substances Data: 270588-96-0(Hazardous Substances Data)

Upstream product

• 100-58-3 phenylmagnesium bromide 
• 321155-39-9 dimethyl(2-pyridinyl)(vinyl)silane 
• 13737-04-7 2-(trimethylsilyl)pyridine 
• 21032-48-4 2-(dimethylhydrosilyl)pyridine 
• 109-04-6 2-bromo-pyridine 
• 536-74-3 phenylacetylene 
• 591-50-4 iodobenzene 
• 100-52-7 benzaldehyde 
• 243468-48-6 bis(2-pyridyldimethylsilyl)methane 

Downstream Products

• 1896-62-4 (E)-benzalacetone 
• 588-73-8 (Z)-β-bromostyrene 
• 588-72-7 [(E)-2-bromoethenyl]benzene 
• 886-65-7 trans,trans-1,4-Diphenyl-1,3-butadiene 
• 38447-06-2 ethyl (2Z,4E)-5-phenyl-2,4-pentadienoate 
• 851286-82-3 C₃₆H₃₆N₂Si₂ 
• 356062-59-4 2-[(1,2-dibromo-2-phenyl-ethyl)-dimethyl-silanyl]-pyridine 
• 103-64-0 bromostyrene 

Relevant articles and documents

Iron-catalyzed, directed oxidative arylation of olefins with organozinc and grignard reagents

(Figure presented) Chelation-controlled arylation of olefins with organozinc or Grignard reagents proceeds in the presence of an iron catalyst, under mild conditions and typically without the need of external ligands, to afford substituted olefins in high

Stereoselective synthesis of multisubstituted butadienes through directed Mizoroki-Heck reaction and homocoupling reaction of vinyl(2-pyridyl)silane

(Chemical Equation Presented) We have developed the homocoupling reaction of alkenyl(2-pyridyl)silanes mediated by Cul and CsF, in which the strong directing effect of the 2-pyridyl group was observed. The homocoupling reaction was successfully integrated with the Mizoroki-Heck reaction of vinyl(2-pyridyl)-silane with aryl halides, enabling a rapid and stereoselective synthesis of multisubstituted butadienes. From a relatively small compound library, it was possible to detect a number of fluorescent butadienes with a wide range of fluorescence color variations (blue to reddish-orange).

2-Pyridylsilane, processes for producing and using the same

The present invention provides a compound which can be purified by conventional acid/base extraction. There is disclosed 2-pyridylsilane of formula (1): wherein R1 represents an alkyl group, etc, R2 and R3 represent an alkyl group, an alkoxy group, etc, R4, R5, R6 and R7 represent a hydrogen atom, a halogen atom, an alkyl group, etc.