27125-61-7

Basic information

• Product Name: Benzenamine, 2-(3-methyl-2-butenyl)-
• Synonyms: 2-prenylaniline;2-(3-methylbut-2-en-1-yl)aniline;Benzenamine,2-(3-methyl-2-butenyl);2-(3'-methyl-2'-butenyl)aniline;2-(3-Methyl-but-2-enyl)-anilin;2-(3-methyl-but-2-enyl)-aniline
• CAS NO: 27125-61-7
• Molecular Formula: C11H15N
• Molecular Weight: 161.247
• Mol File: 27125-61-7.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Benzenamine, 2-(3-methyl-2-butenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 2-(3-methyl-2-butenyl)-(27125-61-7)
• EPA Substance Registry System: Benzenamine, 2-(3-methyl-2-butenyl)-(27125-61-7)

Safety Data

• Hazardous Substances Data: 27125-61-7(Hazardous Substances Data)

Upstream product

• 83036-58-2 prenyl diisopropyl phosphate 
• 62-53-3 aniline 
• 130074-91-8 2,2,2-trifluoro-N-<2-(3-methylbut-2-enyl)phenyl>acetamide 
• 409109-21-3 benzoic acid-[2-(3-methyl-but-2-enyl)-anilide] 
• 115-18-4 2-methyl-3-buten-2-ol 
• 861216-48-0 tert-butyl 2-methylbut-3-en-2-yl carbonate 
• 421571-68-8 1-(3-methylbut-2-en-1-yl)-2-nitrobenzene 
• 1111-97-3 3-chloro-3-methylbut-1-yne 
• 4903-36-0 N-phenyl-benzimidoyl chloride 
• 870-63-3 prenyl bromide 
• 7471-09-2 3-methyl-3-phenylamino-1-butyne 
• 18387-63-8 (3-chloro-3-methylbut-1-yn-1-yl)trimethylsilane 
• 5272-33-3 2-methyl-4-(trimethylsilyl)but-3-yn-2-ol 
• 60173-64-0 N-(1,1-dimethylprop-2-en-1-yl)aniline 

Downstream Products

• 20364-30-1 2,2-dimethyl-1,2,3,4-tetrahydroquinoline 
• 65826-99-5 (±)-2-isopropylindoline 
• 104177-71-1 o-isopentylaniline 

Relevant articles and documents

The first synthesis of 7-prenylisatin

The first synthesis of 7-prenylisatin, an isatin-type antibiotic with prominent activity against Bacillus subtilis, has been accomplished in 16% overall yield from 2-methylbut-3-en-2-ol and aniline via a five-step procedure. The protocol includes the arom

Domino Aryne Annulation via a Nucleophilic-Ene Process

1,2-Benzdiyne equivalents possess the unique property that they can react with two arynophiles through iteratively generated 1,2- and 2,3-aryne intermediates. Upon rational modification on the second leaving group of these aryne precursors, a domino aryne annulation approach was developed through a nucleophilic-ene reaction sequence. Various benzo-fused N-heterocyclic frameworks were achievable under transition metal-free conditions with a broad substrate scope.

Revitalizing the aromatic aza-Claisen rearrangement: Implications for the mechanism of 'on-water' catalysis

For too long the aromatic aza-Claisen rearrangement has been the poor relation of its oxygen counterpart. We demonstrate that on-water catalysis facilitates the rearrangement of reverse N-prenylated naphthylamines and anilines, and transforms the aromatic