277314-01-9

Basic information

• Product Name: [Cu(fla)(idpaH)]ClO₄
• Synonyms: [Cu(fla)(idpaH)]ClO₄
• CAS NO: 277314-01-9
• Molecular Weight: 587.56
• Mol File: 277314-01-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Cu(fla)(idpaH)]ClO₄(CAS DataBase Reference)
• NIST Chemistry Reference: [Cu(fla)(idpaH)]ClO₄(277314-01-9)
• EPA Substance Registry System: [Cu(fla)(idpaH)]ClO₄(277314-01-9)

Safety Data

• Hazardous Substances Data: 277314-01-9(Hazardous Substances Data)

Upstream product

• 577-85-5 3-hydroxyflavone 
• 6711-48-4 N,N-bis-(3-dimethylaminopropyl)amine 

Downstream Products

• 277314-03-1 copper(II)(o-benzoylsalicylato)[3,3'-iminobis(N,N-dimethylpropylamine)]perchlorate 
• 277314-03-1 [Cu(3,3'-iminobis(N,N-dimethylpropylamine))(O-benzoylsalicylate)]ClO₄ 
• 277314-03-1 [Cu(idpaH)(o-bs)]ClO₄ 

Relevant articles and documents

Copper-mediated oxygenation of flavonolate in the presence of a tridentate N-ligand. Synthesis and crystal structures of [Cu(fla)(idpaH)]ClO4 and [Cu(idpaH)(O-bs)]ClO4, [fla = flavonolate, idpaH = 3,3'-iminobis(N,N-dimethylpropylamine), O-bs = O-benzoylsalicylate]

The complexes [Cu(fla)(idpaH)]ClO4 (4) and [Cu(idpaH)(O-bs)]ClO4 (5) (fla = flavonolate, idpaH = 3,3'-iminobis(N,N-dimethylpropylamine), O-bs = O-benzoylsalicylate) have been synthesised and characterised. Complex 5 can be obtained also by the oxygenation of 4 and concomitant CO release. The structures of the compounds have been determined by X-ray diffraction. Complex 4 exhibits distorted trigonal-bipyramidal geometry around the copper(II) ion while complex 5 is distorted square-pyramidal. (C) 2000 Elsevier Science S.A.