281681-23-0

Basic information

• Product Name: Acetamide, N-[3-(acetyloxy)-1-phenylpropyl]-
• CAS NO: 281681-23-0
• Molecular Formula: C13H17NO3
• Molecular Weight: 235.283
• Mol File: 281681-23-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Acetamide, N-[3-(acetyloxy)-1-phenylpropyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetamide, N-[3-(acetyloxy)-1-phenylpropyl]-(281681-23-0)
• EPA Substance Registry System: Acetamide, N-[3-(acetyloxy)-1-phenylpropyl]-(281681-23-0)

Safety Data

• Hazardous Substances Data: 281681-23-0(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 75-05-8 acetonitrile 
• 122-72-5 3-phenylpropyl acetate 
• 316821-53-1 3-[1,3,6,2]dioxazaborocan-2-yl-1-phenyl-propan-1-one O-methyl-oxime 
• 281681-22-9 (E)-3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)propiophenone O-methyloxime 
• 15754-20-8 (E)-acetophenone O-methyloxime 
• 281681-20-7 3-[(4R,5R)-4,5-Bis(1-methoxycyclopentyl)-1,3,2-dioxoborolan-2-yl]propiophenone O-methyloxime 
• 3646-50-2 3-Amino-3-phenylpropionic acid 
• 81548-17-6 N-(3-hydroxy-1-phenylpropyl)acetamide 
• 75-36-5 acetyl chloride 
• 108-24-7 acetic anhydride 
• 14593-04-5 3-amino-3-phenyl-1-propanol 
• 281681-21-8 3-[(4S,5S)-4,5-Bis(1-methoxycyclopentyl)-1,3,2-dioxoborolan-2-yl]propiophenone O-methyloxime 
• 100-42-5 styrene 

Downstream Products

• 14593-04-5 3-amino-3-phenyl-1-propanol 
• 677006-24-5 N-(3-hydroxy-1-phenylpropyl)thioacetamide 
• 677006-30-3 2-methyl-4-phenyl-5,6-dihydro-4H-1,3-thiazine 
• 677006-18-7 3-thioacetylamino-3-phenylpropyl acetate 

Relevant articles and documents

C-H Amination via Electrophotocatalytic Ritter-Type Reaction

A method for C-H bond amination via an electrophotocatalytic Ritter-Type reaction is described. The reaction is catalyzed by a trisaminocyclopropenium (TAC) ion in an electrochemical cell under irradiation. These conditions convert benzylic C-H bonds to acetamides without the use of a stoichiometric chemical oxidant. A range of functionality is shown to be compatible with this transformation, and several complex substrates are demonstrated.

A convenient synthesis of dihydro- and tetrahydro-1,3-thiazine derivatives from β-aryl-β-amino acids

A facile synthesis of 2-alkyl-4-aryl-5,6-dihydro-4H-1,3-thiazines and cis-2-alkyl-4-aryl-3,4,5,6-tetrahydro-2H-1,3-thiazines with potential therapeutic interest was achieved starting from readily accessible β-aryl-β-amino acids.

'Transmitted' remote double diastereoselection effects on the asymmetric reduction of β-boronate oxime ethers

Remote asymmetric induction in the reduction of a homochiral β-boronate oxime ether to the corresponding amine failed to provide asymmetric induction with a chiral reducing agents, but use of a chiral reducing agent produced extreme double diastereoselection effects which show that remote asymmetry can be 'transmitted' by suitable choice of a 'partner' molecule. (C) 2000 Published by Elsevier Science Ltd.