28267-98-3

Basic information

• Product Name: Benzenecarboximidamide,N-hydroxy-N'-methyl-
• Synonyms: Benzamidoxime,N-methyl- (8CI); N-Methylbenzamide oxime; NSC 114496
• CAS NO: 28267-98-3
• Molecular Formula: C8H10 N2 O
• Molecular Weight: 150.18
• Mol File: 28267-98-3.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzenecarboximidamide,N-hydroxy-N'-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenecarboximidamide,N-hydroxy-N'-methyl-(28267-98-3)
• EPA Substance Registry System: Benzenecarboximidamide,N-hydroxy-N'-methyl-(28267-98-3)

Safety Data

• Hazardous Substances Data: 28267-98-3(Hazardous Substances Data)

Upstream product

• 10349-15-2 3-(Acetylamino)-4-phenylfurazan 
• 74-89-5 methylamine 
• 932-90-1 Benzaldoxime 
• 698-16-8 benzohydroximoyl chloride 
• 1456-22-0 3-phenyl-4H-[1,2,4]oxadiazol-5-one 
• 934-16-7 phenylhydroxamoyl chloride 
• 110621-89-1 3-phenyl-5-trinitromethyl-1,2,4-oxadiazole 
• 3201-46-5 4-methyl-3-phenyl-1,2,4-oxadiazol-5(4H)-one 

Downstream Products

• 65007-79-6 Methylbenzamidin 
• 137340-72-8 3-phenyl-4-methyl-Δ²-dihydro-1,2,4-oxadiazine-5-one 
• 888-71-1 3,5-diphenyl-1,2,4-oxadiazole 
• 20594-92-7 3,5-diphenyl-1,2,4-oxadiazole-4-oxide 
• 141693-82-5 3-phenyl-4-methyl-1,2,4-thiadiazole-5(4H)-thione 
• 64671-78-9 3-phenyl-4-methyl-1,2,4-thiadiazole-5(4H)-one 
• 632-14-4 1,1,3-trimethylurea 
• 63105-07-7 3-methyl-4-phenyl-3H-[1,2,3,5]oxathiadiazole 2-oxide 
• 139698-08-1 3,4-diphenyl-Δ²-dihydro-1,2,4-oxadiazine-5-thione 
• 139698-07-0 3-phenyl-4-methyl-Δ²-dihydro-1,2,4-oxadiazine-5-thione 

Relevant articles and documents

Reduction of substituted 5-(nitromethyl)-3-phenyl-1,2,4-oxadiazoles

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Cycloadditions of nitrile oxides to amidoximes. A general synthesis of 3,5-disubstituted 1,2,4-oxadiazole-4-oxides

The cycloaddition of nitrile oxides to amidoximes is a general method for the synthesis of 3,5-disubstituted 1,2,4-oxadiazole-4-oxides with the same or different substituents. The yields are only moderate since an equivalent amount of the nitrile oxide is consumed by reaction with the amine released in the fragmentation of the primary cycloadducts and reforms the amidoxime. With excess nitrile oxides the 1,2,4-oxadiazole-4-oxides undergo a disproportionation reaction to yield nitroso carbonyl intermediates and 1,2,4-oxadiazoles.

Selectivity in Cycloadditions, XVI. Stereochemistry and Cleavage of the Bisadduct of Benzonitrile Oxide with Pyridine.

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