28586-59-6Relevant articles and documents
Synthesis of 4H-3,1-benzoxazines by the reaction of o-(N-acylamino)benzyl alcohols with dast
Nisyio, Takehiko,Kurokawa, Yukiko,Narasaki, Yoshiya,Tokunaga, Tatsuhiro
, p. 247 - 254 (2007/10/03)
The treatment of o-(N-acylamino)benzyl alcohols (1) with DAST afforded the dehydrative cyclization product, 4H-3,1-benzoxazines (4) and the hydroxy replacement product, o-(N-acylamino)benzyl fluorides (5). The yields of benzoxazines (4) and fluorides (5)
Heterocyclic 8?-Systems, 15. Investigations on Indole 2,3-Oxides: Sythesis of 3-Hydroxyindoles via Intramolecular Wittig-Rearrangement of 1,2-Dihydro-4H-3,1-benzoxazines
Schmidt, Richard R.,Beitzke, Bernhard
, p. 2115 - 2135 (2007/10/02)
Investigations to trap indole 2,3-oxides 11 by base catalyzed ring contraction of 4H-3,1-benzoxazines 3 led in the system KNH2/NH3 to 3-hydroxy-3H-indoles 7.The N-methylbenzoxazinium salts 15, obtained from 3 and FSO3CH3, yielded with ethoxide under kinet