290827-84-8

Basic information

• Product Name: diphenyl[4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)phenyl]phosphine oxide
• Synonyms: diphenyl[4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)phenyl]phosphine oxide
• CAS NO: 290827-84-8
• Molecular Weight: 624.381
• Mol File: 290827-84-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: diphenyl[4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)phenyl]phosphine oxide(CAS DataBase Reference)
• NIST Chemistry Reference: diphenyl[4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)phenyl]phosphine oxide(290827-84-8)
• EPA Substance Registry System: diphenyl[4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)phenyl]phosphine oxide(290827-84-8)

Safety Data

• Hazardous Substances Data: 290827-84-8(Hazardous Substances Data)

Upstream product

• 5525-40-6 (4-bromophenyl)diphenylphosphine oxide 
• 195324-87-9 1-bromo-4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)benzene 
• 589-87-7 1,4-bromoiodobenzene 
• 25291-17-2 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene 
• 290827-93-9 diphenyl[4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)phenyl]phosphane 
• 2043-57-4 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane 

Downstream Products

• 290827-93-9 diphenyl[4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)phenyl]phosphane 

Relevant articles and documents

New approaches to fluorinated ligands and their application in catalysis

Simple and generic approaches to fluorous soluble ligands have been developed and applied to the synthesis of various fluorinated arylphosphines including polymeric ones. The utility of some of these ligands has been demonstrated in catalysis in supercritical CO2 (scCO2) and fluorous solvents.

Separation of "light fluorous" reagents and catalysts by fluorous solid-phase extraction: Synthesis and study of a family of triarylphosphines bearing linear and branched fluorous tags

Practical syntheses of new triarylphosphines bearing both linear and branched fluorous tags (Rf) are reported. The phosphines have one, two, or all three aryl rings bearing fluorous tags: (Ph)3-nP(C6H4 (CH2)mRf)n. Fluorous-organic partition coefficients have been measured and the retention properties of both the phosphines and the derived phosphine oxides on fluorous reverse phase silica have been studied. While applications relying on liquid-liquid extractive separations of these phosphines may be limited to those bearing three fluorous chains, the technique of solid phase extraction should be broadly applicable to phosphines, phosphine oxides, and derived metal complexes. A parallel platinum-catalyzed allylation of aldehydes with fluorous allyl stannanes illustrates the usefulness of the new fluorous ligands in small-scale synthesis.