29124-68-3

Basic information

• Product Name: Acetamide, N-(2-ethenylphenyl)-
• CAS NO: 29124-68-3
• Molecular Formula: C10H11NO
• Molecular Weight: 161.203
• Mol File: 29124-68-3.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: Acetamide, N-(2-ethenylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetamide, N-(2-ethenylphenyl)-(29124-68-3)
• EPA Substance Registry System: Acetamide, N-(2-ethenylphenyl)-(29124-68-3)

Safety Data

• Hazardous Substances Data: 29124-68-3(Hazardous Substances Data)

Upstream product

• 74-85-1 ethene 
• 614-76-6 N-acetyl-2-bromoaniline 
• 103-84-4 Acetanilid 
• 7486-35-3 tri-n-butyl(vinyl)tin 
• 552-89-6 2-nitro-benzaldehyde 
• 579-71-5 2-nitrostyrene 
• 19591-17-4 o-iodoacetanilide 
• 3867-18-3 2-vinylaniline 
• 75-36-5 acetyl chloride 
• 108-24-7 acetic anhydride 

Downstream Products

• 120-72-9 indole 
• 91-63-4 2-methylquinoline 
• 576-15-8 N-acetylindole 
• 33098-65-6 2-acetamido-1-ethylbenzene 
• 681427-62-3 N-prop-2-ynyl-N-(2-vinyl-phenyl)acetamide 
• 947689-00-1 C₁₅H₁₉NO₃ 
• 612-62-4 2-Chloroquinoline 
• 23543-66-0 N-acetyl-3-methylindole 
• 13303-72-5 3-methyl-N-acetylindoline-2-ol 
• 1195264-48-2 2-vinylthioacetanilide 
• 173436-68-5 2-methyl-1-[(4-methylphenyl)sulfonyl]-1H-indole 
• 1180844-33-0 N-tosyl-N-(2-vinylphenyl)acetamide 
• 947689-01-2 C₂₇H₂₈NO₆P 
• 3867-18-3 2-vinylaniline 

Relevant articles and documents

Dehydrative Beckmann rearrangement and the following cascade reactions

The Beckmann rearrangement has been predominantly studied for the synthesis of amide and lactam. By strategically using the in situ generated Appel's salt or Mitsunobu's zwitterionic adduct as the dehydrating agent, a series of Beckmann rearrangement and following cascade reactions have been developed herein. The protocol allows the conversion of various ketoximes into amide, thioamide, tetrazole and imide products in modular procedures. The generality and tolerance of functionalities of this method have been demonstrated.

Intermolecular and intramolecular pauson-khand reactions of functionalized Allenes

Pauson-Khand reactions of functionalized allenes with different alkynes give cyclopentenones with generally high regio-and stereoselectivities. The allenes react through their external double bonds, giving cyclopentenones with exocyclic double bond at their β positions and predominantly with E stereochemistry. Some intramolecular reactions with allenynes connected through aromatic rings are described. These give the corresponding heterocycles with moderate to good yields. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.

Novel formation of indoles and 3,1-benzoxazines from o-alkenylanilides and dimethyl(methylthio)sulfonium trifluoromethanesulfonate

The reaction of dimethyl(methylthio)sulfonium trifluoromethanesulfonate (DMTST) with o-allylphenol gave 2-methylthiomethyl-2,3-dihydrobenzofuran in 97% yield. The reaction of DMTST with N-tosyl-o-isopropenylanilide followed by the addition of aq sodium carbonate afforded N-tosyl-3-methylindole in 88% yield, whereas N-tosyl-o-vinylanilide afforded N-tosylindoline in 85% yield.