947689-01-2

Basic information

• Product Name: C₂₇H₂₈NO₆P
• Synonyms: C₂₇H₂₈NO₆P
• CAS NO: 947689-01-2
• Molecular Weight: 493.496
• Mol File: 947689-01-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₂₇H₂₈NO₆P(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₇H₂₈NO₆P(947689-01-2)
• EPA Substance Registry System: C₂₇H₂₈NO₆P(947689-01-2)

Safety Data

• Hazardous Substances Data: 947689-01-2(Hazardous Substances Data)

Upstream product

• 19591-17-4 o-iodoacetanilide 
• 29124-68-3 N-(2-vinylphenyl)acetamide 
• 947689-00-1 C₁₅H₁₉NO₃ 
• 2524-64-3 chlorophosphoric acid diphenyl ester 

Relevant articles and documents

(R/S)-BINOL-α-phosphoryloxy enecarbamate-mediated and (R/S)-Titanium(IV) BINOLates-catalyzed enantioselective intramolecular heck/aza-diels-alder cycloaddition (IHADA): An expedient methodology

An (R/S)-titanium(IV) BINOLate-catalyzed highly enantioselective intramolecular Heck/aza-Diels-Alder cycloaddition (IHADA) cascade was developed to prepare tetrahydropyridoindoles (tHPs) and octahydropyrazinopyridoindoles (oHPPs) from in situ generated (R/S)-BINOL α-phosphoryloxy carbamate (αPPC2) in one pot. Chiral cooperativity between (R/S)-αPPC2 and (R/S)-titanium(IV) BINOLate was observed and successfully utilized for the construction of various tHPs (7 examples) and oHPPs (17 examples). Copyright