29949-92-6

Basic information

• Product Name: Phosphorane, (chloromethylene)triphenyl-
• CAS NO: 29949-92-6
• Molecular Formula: C19H16ClP
• Molecular Weight: 310.763
• Mol File: 29949-92-6.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Phosphorane, (chloromethylene)triphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphorane, (chloromethylene)triphenyl-(29949-92-6)
• EPA Substance Registry System: Phosphorane, (chloromethylene)triphenyl-(29949-92-6)

Safety Data

• Hazardous Substances Data: 29949-92-6(Hazardous Substances Data)

Upstream product

• 111441-95-3 (chloromethyl)triphenylphosphonium bromide 
• 5293-84-5 chloromethyltriphenylphosphonium chloride 

Downstream Products

• 54157-27-6 (2E,4E)-2-Chloro-3-methyl-5-phenyl-penta-2,4-dienoic acid methyl ester 
• 54157-26-5 (2Z,4E)-2-Chloro-3-methyl-5-phenyl-penta-2,4-dienoic acid methyl ester 
• 177799-61-0 Z-2-chloro-1-<4-(N,N-dimethylamino)phenyl>ethene 
• 410069-57-7 (E)-2-chloro-1-[2-(N,N-dimethylamino)phenyl]ethene 
• 1079080-10-6 C₁₂H₁₃ClO₂ 
• 80507-23-9 Ni(CHClP(C₆H₅)3)(C₅H₅)P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=[Ni(CHClP(C₆H₅)3)(C₅H₅)P(C₆H₅)3]PF₆ 
• 32613-25-5 [(η5-cyclopentadienyl)ruthenium(II)(triphenylphosphine)(carbonyl)(chloride)] 
• 410069-58-8 2-chloro-1-[3-(N,N-dimethylamino)phenyl]ethene 
• 18829-56-6 (E)-2-Nonenal 
• 2548-87-0 (E)-2-Octenal 
• 18829-55-5 (E)-2-Heptenal 
• 85609-00-3 (E/Z)-2-chloro-1-<4-(N,N-dimethylamino)phenyl>ethene 
• 323199-49-1 2-(2-bromophenylmethyl)-1-(chloromethylene)cyclohexane 
• 221272-69-1 1-[4-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxymethyl)-5-(2-chloro-vinyl)-tetrahydro-furan-2-yl]-5-methyl-1H-pyrimidine-2,4-dione 

Relevant articles and documents

Radical Cations of Bridged Bicycloocta-2,5-dienes - Open-Shell Bis-Homoaromatic Systems

The radical cations of a series of bridged bicycloocta-2,5-dienes have been generated by photoinduced electron transfer to strong electron acceptors (chloranil, fluoranil) in solution.Chemically induced dynamic nuclear polarization effects observed

Regiochemistry in aryl radical cyclization onto methylenecycloalkanes

Bu3SnH-mediated aryl radical cyclization onto methylenecycloalkanes having a phenylthio, an ester, or a nitrile group at the terminus of the alkenic bond provides exclusively exo cyclization products. The results are in sharp contrast to those reported for nonsubstituted methylenecycloalkanes, which give exclusively endo cyclization products. Formation of endo cyclization products has been suggested to be a result of a consecutive 5-exo cyclization of an aryl radical and neophyl rearrangement. The exo-selective aryl radical cyclization offers a new method for synthesizing fused aromatic compounds containing a benzylic quaternary carbon atom.

Preparation and Wittig reactions of an α-keto amino acid derivative

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