30068-21-4

Basic information

• Product Name: Benzenemethanol, a-ethyl-4-methoxy-a-methyl-
• Synonyms: α-ethyl-α-methyl-4-methoxy-benzenemethanol;2-(4-methoxyphenyl)-2-butanole;2-(4-methoxyphenyl)butan-2-ol;2-(p-methoxyphenyl)-2-butanol;2-(4-Methoxyphenyl)-2-butanol
• CAS NO: 30068-21-4
• Molecular Formula: C11H16O2
• Molecular Weight: 180.247
• Mol File: 30068-21-4.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-ethyl-4-methoxy-a-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-ethyl-4-methoxy-a-methyl-(30068-21-4)
• EPA Substance Registry System: Benzenemethanol, a-ethyl-4-methoxy-a-methyl-(30068-21-4)

Safety Data

• Hazardous Substances Data: 30068-21-4(Hazardous Substances Data)

Upstream product

• 557-20-0 diethylzinc 
• 586-37-8 1-(3-Methoxyphenyl)ethanone 
• 1257661-31-6 C₁₇H₂₇BO₃ 
• 10467-10-4 ethylmagnesium iodide 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 78-93-3 butanone 
• 75-03-6 ethyl iodide 
• 925-90-6 ethylmagnesium bromide 
• 1201898-86-3 (S)-2-[2-(4-methoxyphenyl)but-2-yl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 100-66-3 methoxybenzene 
• 99-93-4 4-Hydroxyacetophenone 
• 97-94-9 triethyl borane 
• 30068-20-3 2-(4-hydroxy-phenyl)-butan-2-ol 

Downstream Products

• 21758-19-0 4-(but-1-en-2-yl)anisole 
• 38454-62-5 (E)-2-(4-methoxyphenyl)but-2-ene 
• 93320-63-9 1.2-Dimethyl-1-(p-anisyl)-3.3.4.4-tetracyanocyclobutan 
• 35144-34-4 erythro-3-(4-methoxyphenyl)butan-2-ol 
• 29886-67-7 3-(4'-Hydroxyphenyl)thiophene 
• 82437-75-0 3-(4-methoxy-phenyl)-thiophene 
• 74385-28-7 C₂₀H₂₆O₂ 
• 141298-95-5 1-(2-Chloro-1-methylene-propyl)-4-methoxy-benzene 
• 74385-20-9 meso-3,4-dimethyl-3,4 bis(4'-methoxyphenyl)hexane 
• 51431-73-3 1-(but-2-en-2-yl)-4-methoxybenzene 
• 38454-63-6 Z-2-(4-methoxyphenyl)-2-butene 

Relevant articles and documents

Compound with cinnamon fragrance as well as preparation method and application thereof

The invention relates to a compound with cinnamon fragrance as well as a preparation method and application thereof. The compound has the following structural formula, wherein the structural formula can be named as 2-decenoic acid-2-(4-methoxy)-phenyl-2-butyl ester. The provided compound has the advantages of obvious cinnamon aroma, rich aroma, lasting aroma and good stability, and enriches the sources of cinnamon aroma. When the essence is prepared in different periods, the compound has consistent cinnamon aroma, so that the required aroma can be accurately mastered.

Enantioselective α-arylation of O-carbamates via sparteine-mediated lithiation and Negishi cross-coupling

A general and highly enantioselective arylation of carbamates derived from primary alcohols was developed by combining Hoppe's sparteine-mediated asymmetric lithiation with Negishi cross-coupling. Coupled with Aggarwal's lithiation-borylation sequence, the current method provides a short and divergent access to a variety of enantioenriched secondary and tertiary benzylic alcohols.

CHIRAL DIAMINE COMPOUNDS FOR THE PREPARATION OF CHIRAL ALCOHOL AND CHIRAL AMINE

A process for the stereoselective preparation of a chiral alcohol or a chiral amine, the process comprising reacting a first prochiral reactant selected from the group consisting of a ketone, an aldehyde, and an inline, with a second reactant comprising a Grignard reagent, in the presence of a chiral trans-diamim of formula (1) as defined herein. Also provided is the use of the chiral trans-diamine of formula (1) in a Grignard reaction and the chiral trans-diamines per se.