30270-61-2

Basic information

• Product Name: (2S,3aS,9bS)-6,7,8-Trimethoxy-2-propyl-2,3,3a,9b-tetrahydro-furo[3,2-c]isochromen-5-one
• CAS NO: 30270-61-2
• Molecular Weight: 322.358
• Mol File: 30270-61-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S,3aS,9bS)-6,7,8-Trimethoxy-2-propyl-2,3,3a,9b-tetrahydro-furo[3,2-c]isochromen-5-one(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3aS,9bS)-6,7,8-Trimethoxy-2-propyl-2,3,3a,9b-tetrahydro-furo[3,2-c]isochromen-5-one(30270-61-2)
• EPA Substance Registry System: (2S,3aS,9bS)-6,7,8-Trimethoxy-2-propyl-2,3,3a,9b-tetrahydro-furo[3,2-c]isochromen-5-one(30270-61-2)

Safety Data

• Hazardous Substances Data: 30270-61-2(Hazardous Substances Data)

Upstream product

• 123731-68-0 (S)-1,2-epoxypentane 
• 71539-28-1 7-O-demethylmonocerin 
• 74-88-4 methyl iodide 
• 1442635-86-0 2-(4-isopropoxy-3,5-dimethoxybenzyl)-1,3-dithiane 
• 71539-29-2 fusarentin 6-methyl ether 
• 1442635-91-7 (S)-3-((S)-2-hydroxypentyl)-7-isopropoxy-6,8-dimethoxyisochroman-1-one 
• 1442635-90-6 (S)-1-((S)-7-isopropoxy-6,8-dimethoxy-1-oxoisochroman-3-yl)pentan-2-yl propionate 
• 1442635-89-3 (2S,4S)-2-hydroxy-1-(4-isopropoxy-3,5-dimethoxyphenyl)heptan-4-yl propionate 
• 1442635-88-2 (S)-4-hydroxy-1-(4-isopropoxy-3,5-dimethoxyphenyl)heptan-2-one 
• 1442635-87-1 (S)-1-(2-(4-isopropoxy-3,5-dimethoxybenzyl)-1,3-dithian-2-yl)pentan-2-ol 

Downstream Products

• 28890-33-7 (2R,3aR,9bR)-2,3,3a,9b-tetrahydro-6-hydroxy-7,8-dimethoxy-2-propyl-5H-furo(3,2-c)(2)benzopyran-5-one 
• 28890-33-7 (+/-)-monocerin 
• 28890-33-7 monocerin 
• 28890-33-7 (2S,3aS,9bS)-6-Hydroxy-7,8-dimethoxy-2-propyl-2,3,3a,9b-tetrahydro-furo[3,2-c]isochromen-5-one 

Relevant articles and documents

Asymmetric total synthesis of fusarentin 6-methyl ether and its biomimetic transformation into fusarentin 6,7-dimethyl ether, 7-O-demethylmonocerin, and (+)-monocerin

A concise asymmetric total synthesis of a fusarentin ether (1) with sequential biomimetic transformation to its analogues fusarentin 6,7-dimethyl ether (2), 7-O-demethylmonocerin (3), and (+)-monocerin (4) has been accomplished. The cis-fused furobenzopyranones of 7-O-demethylmonocerin (3) and (+)-monocerin (4) were efficiently constructed via an intramolecular nucleophilic trapping of a quinonemethide intermediate, which was obtained by benzylic oxidation of fusarentin 6-methyl ether (1) using hypervalent iodine reagent.