3042-67-9

Basic information

• Product Name: 2-(4-Chlorobenzyl)naphthalene
• Synonyms: 2-(4-Chlorobenzyl)naphthalene
• CAS NO: 3042-67-9
• Molecular Formula: C17H13Cl
• Molecular Weight: 252.743
• Mol File: 3042-67-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-(4-Chlorobenzyl)naphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-Chlorobenzyl)naphthalene(3042-67-9)
• EPA Substance Registry System: 2-(4-Chlorobenzyl)naphthalene(3042-67-9)

Safety Data

• Hazardous Substances Data: 3042-67-9(Hazardous Substances Data)

Usage

Chemical structure

Consists of a naphthalene core with a 4-chlorobenzyl group attached at the 2-position.

Appearance

White crystalline solid.

Solubility

Insoluble in water, soluble in organic solvents.

Uses

主要用于合成各种有机化合物, also used as a research tool in the study of chemical reactions and processes.

Safety precautions

May pose health hazards if inhaled or ingested, handle with care and take proper safety precautions.

Upstream product

• 147022-24-0 (4-chlorophenyl)(naphthalene-2-yl)methanol 
• 53006-31-8 2-[1-(4-Chloro-phenyl)-meth-(E)-ylidene]-1,2,3,4-tetrahydro-naphthalen-1-ol 
• 7495-98-9 (4-chlorophenyl)(naphthalen-2-yl)methanone 
• 21473-01-8 2-naphthalenylmagnesium bromide 
• 104-88-1 4-chlorobenzaldehyde 
• 1592-38-7 2-Naphthalenemethanol 
• 7519-91-7 tris(4-chlorophenyl)boroxine 
• 1679-18-1 4-Chlorophenylboronic acid 
• 17666-88-5 1-(naphthalen-2-yl)butan-1-one 
• 22584-81-2 (4-chloro-benzyl)-dihydroxy-borane 

Downstream Products

• 70557-76-5 2-(4-chlorobenzyl)-1,4-naphthoquinone 

Relevant articles and documents

Arylketones as Aryl Donors in Palladium-Catalyzed Suzuki-Miyaura Couplings

Herein, we report the arylation, alkylation, and alkenylation of aryl ketones via a palladium-catalyzed Suzuki-Miyaura cross-coupling reaction. The use of the pyridine-oxazoline ligand is the key to the cleavage of the unstrained C-C bond. The late-stage arylation of aryl ketones derived from drugs and natural products demonstrated the synthetic utility of this protocol.

Direct cross-coupling of benzyl alcohols to construct diarylmethanes via palladium catalysis

A direct arylation to furnish diarylmethanes from benzyl alcohols was realized through Pd(PPh3)4-catalyzed Suzuki-Miyaura coupling via benzylic C-O activation in the absence of any additives. The arylation is compatible with various functional groups. This development provides an atom- and step-economic way to approach a diarylmethane scaffold under mild and environmentally benign conditions. This journal is

AROMATIZATION OF ALIPHATIC COMPOUNDS - V. m-DIALKIYL-BENZENES AND 2-BENZYL-NAPHTALENES

Same cyclohexadienols, when heated at 220 deg C with PyHCl, gave, through dehydration and isomerisation, the corresponding benzene derivatives.So 2,6-dibenzyliden-cyclohexanols gave m-dibenzyl-benzenes, 2-benzyliden-1-tetralols gave 2-benzyl-naphtalenes a