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30556-86-6

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30556-86-6 Usage

General Description

3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctylamine is a chemical compound with the molecular formula C8F13N. It is a long-chain fluorinated amine that is used as a surfactant and a surface modifier in various industrial applications. 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctylamine is known for its unique properties, including its low surface tension and high thermal stability. It is commonly used in the production of high-performance coatings, adhesives, and lubricants. Additionally, 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctylamine has been studied for its potential as a foaming agent and as a component in materials for oil and water repellency. Due to its fluorinated nature, this chemical compound has raised concerns about its potential environmental and health impacts, and it is subject to regulation in some jurisdictions.

Check Digit Verification of cas no

The CAS Registry Mumber 30556-86-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,0,5,5 and 6 respectively; the second part has 2 digits, 8 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 30556-86:
(7*3)+(6*0)+(5*5)+(4*5)+(3*6)+(2*8)+(1*6)=106
106 % 10 = 6
So 30556-86-6 is a valid CAS Registry Number.

30556-86-6Synthetic route

8-azido-1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorooctane
62571-55-5

8-azido-1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorooctane

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In diethyl ether at 20℃; under 5171.62 Torr;88%
With hydrazine hydrate; nickel In water at 60℃; for 8h;83%
With lithium aluminium tetrahydride In tetrahydrofuran77%
1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane
2043-57-4

1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

Conditions
ConditionsYield
With sodium azide; N2H4*H2O-Raney Ni; hydrazine hydrate Multistep reaction;
Multi-step reaction with 2 steps
1: sodium azide; Aliquot 336 / H2O / Heating
2: H2 / Pd/C / diethyl ether / 2585.74 Torr
View Scheme
Multi-step reaction with 2 steps
1: NaN3 / dimethylformamide / 72 h / 20 °C
2: 8.1 g / H2 / Pd/C / diethyl ether / 12 h / 5250.42 Torr
View Scheme
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

acryloyl chloride
814-68-6

acryloyl chloride

C11H8F13NO

C11H8F13NO

Conditions
ConditionsYield
With triethylamine In chloroform Solvent; Concentration; Cooling with ice;99%
isocyanate de chloro-4 phenoxysulfonyle
14793-41-0

isocyanate de chloro-4 phenoxysulfonyle

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

C15H10ClF13N2O4S

C15H10ClF13N2O4S

Conditions
ConditionsYield
In toluene at 0℃; for 0.0833333h; Addition;98%
Glyoxal
131543-46-9

Glyoxal

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

(3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-octyl)-[2-[(E)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octylimino]-eth-(E)-ylidene]-amine

(3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-octyl)-[2-[(E)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octylimino]-eth-(E)-ylidene]-amine

Conditions
ConditionsYield
In methanol at 20℃; for 48h; Condensation;98%
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

Isopropyl isocyanate
1795-48-8

Isopropyl isocyanate

N-isopropyl-N'-(1H,1H,2H,2H-perfluorooctyl)urea

N-isopropyl-N'-(1H,1H,2H,2H-perfluorooctyl)urea

Conditions
ConditionsYield
In dichloromethane at 20℃; for 0.5h;95%
2,2-bis(hydroxymethyl)propionic acid
4767-03-7

2,2-bis(hydroxymethyl)propionic acid

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

3-Hydroxy-2-hydroxymethyl-2-methyl-N-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-propionamide
137607-95-5

3-Hydroxy-2-hydroxymethyl-2-methyl-N-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-propionamide

Conditions
ConditionsYield
With tertiary amine; (benzotriazo-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate94%
3-(tert-butyloxycarbonylamino)propionic acid
3303-84-2

3-(tert-butyloxycarbonylamino)propionic acid

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

C16H19F13N2O3
1025018-36-3

C16H19F13N2O3

Conditions
ConditionsYield
Stage #1: 3-(tert-butyloxycarbonylamino)propionic acid With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 0.166667h;
Stage #2: 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine In dichloromethane at 20℃; for 12h;
94%
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

epichlorohydrin
106-89-8

epichlorohydrin

1-Chloro-3-[(3-chloro-2-hydroxy-propyl)-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-amino]-propan-2-ol

1-Chloro-3-[(3-chloro-2-hydroxy-propyl)-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-amino]-propan-2-ol

Conditions
ConditionsYield
at 40 - 45℃; for 15h;93%
Boc-Asp-OH
13726-67-5

Boc-Asp-OH

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

[(S)-1,2-Bis-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octylcarbamoyl)-ethyl]-carbamic acid tert-butyl ester

[(S)-1,2-Bis-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octylcarbamoyl)-ethyl]-carbamic acid tert-butyl ester

Conditions
ConditionsYield
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane92%
With (benzotriazo-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate; triethylamine In acetonitrile for 3h; Ambient temperature;66%
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

Z,3-Perfluoropentyl,3-fluoro-propenoate d'ethyle
172286-94-1

Z,3-Perfluoropentyl,3-fluoro-propenoate d'ethyle

(Z)-4,4,5,5,6,6,7,7,8,8,8-Undecafluoro-3-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octylamino)-oct-2-enoic acid ethyl ester

(Z)-4,4,5,5,6,6,7,7,8,8,8-Undecafluoro-3-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octylamino)-oct-2-enoic acid ethyl ester

Conditions
ConditionsYield
With triethylamine In dichloromethane for 16h; Substitution; Heating;90%
formic acid
64-18-6

formic acid

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

(1H,1H,2H,2H-perfluorooctyl)-methylamine
26577-70-8

(1H,1H,2H,2H-perfluorooctyl)-methylamine

Conditions
ConditionsYield
Stage #1: formic acid; 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine With acetic anhydride In tetrahydrofuran at 20℃; for 3h;
Stage #2: With dimethylsulfide borane complex In tetrahydrofuran for 5h; Heating / reflux;
Stage #3: With hydrogenchloride; methanol more than 3 stages;
89%
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

bromoacetic acid
79-08-3

bromoacetic acid

2-Bromo-N-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-acetamide
132711-10-5

2-Bromo-N-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-acetamide

Conditions
ConditionsYield
With dicyclohexyl-carbodiimide In dichloromethane at 20℃; for 3h;88%
With dicyclohexyl-carbodiimide In dichloromethane at 20℃;
formaldehyd
50-00-0

formaldehyd

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

N,N-dimethyl-2-(perfluorohexyl)ethylamine
84070-78-0

N,N-dimethyl-2-(perfluorohexyl)ethylamine

Conditions
ConditionsYield
With acetic acid at 90℃; for 3h;85%
With formic acid for 10h; Heating; Yield given;
With acetic acid at 0 - 90℃; Eschweiler-Clarke reaction;
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

2-bromobutyric acid ethyl ester
533-68-6

2-bromobutyric acid ethyl ester

2-(3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-octylamino)-butyric acid ethyl ester
142349-76-6

2-(3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-octylamino)-butyric acid ethyl ester

Conditions
ConditionsYield
With N-benzyl-N,N,N-triethylammonium chloride; potassium carbonate In acetonitrile at 70℃;83%
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

Glyoxilic acid
298-12-4

Glyoxilic acid

[(E)-3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-octylimino]-acetic acid

[(E)-3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-octylimino]-acetic acid

Conditions
ConditionsYield
In methanol at 0℃; for 1h; Condensation;83%
(2-formylphenyl)(diphenyl)phosphine
50777-76-9

(2-formylphenyl)(diphenyl)phosphine

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

C27H19F13NP

C27H19F13NP

Conditions
ConditionsYield
In methanol for 12h;83%
Ethyl 2-bromohexanoate
615-96-3

Ethyl 2-bromohexanoate

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

2-(3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-octylamino)-hexanoic acid ethyl ester
142349-78-8

2-(3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-octylamino)-hexanoic acid ethyl ester

Conditions
ConditionsYield
With N-benzyl-N,N,N-triethylammonium chloride; potassium carbonate In acetonitrile at 70℃;82%
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

acrylonitrile
107-13-1

acrylonitrile

3-(3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-octylamino)-propionitrile
185798-61-2

3-(3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-octylamino)-propionitrile

Conditions
ConditionsYield
In ethanol for 6h; Ambient temperature;82%
2-bromo-pentanoic acid ethyl ester
615-83-8

2-bromo-pentanoic acid ethyl ester

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

2-(3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-octylamino)-pentanoic acid ethyl ester
142349-77-7

2-(3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-octylamino)-pentanoic acid ethyl ester

Conditions
ConditionsYield
With N-benzyl-N,N,N-triethylammonium chloride; potassium carbonate In acetonitrile at 70℃;81%
diethylene glycol monoiodide
130536-69-5

diethylene glycol monoiodide

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

2-{2-[[2-(2-Hydroxy-ethoxy)-ethyl]-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-amino]-ethoxy}-ethanol

2-{2-[[2-(2-Hydroxy-ethoxy)-ethyl]-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-amino]-ethoxy}-ethanol

Conditions
ConditionsYield
With sodium carbonate In acetonitrile81%
isocyanate de trimethyl-2,4,6 phenoxysulfonyle
17648-64-5

isocyanate de trimethyl-2,4,6 phenoxysulfonyle

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

C18H17F13N2O4S

C18H17F13N2O4S

Conditions
ConditionsYield
In toluene at 0℃; for 0.1h; Addition;81%
succinic acid anhydride
108-30-5

succinic acid anhydride

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

N-(3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-octyl)-succinamic acid
157103-00-9

N-(3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-octyl)-succinamic acid

Conditions
ConditionsYield
In chloroform at -20℃;80%
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

ethyl 3-perfluorononyl-3-fluoropropenoate

ethyl 3-perfluorononyl-3-fluoropropenoate

(Z)-4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-Nonadecafluoro-3-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octylamino)-dodec-2-enoic acid ethyl ester
693825-91-1

(Z)-4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-Nonadecafluoro-3-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octylamino)-dodec-2-enoic acid ethyl ester

Conditions
ConditionsYield
With triethylamine In diethyl ether for 48h; Heating;80%
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

(Z)-3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Hexadecafluoro-dec-2-enoic acid ethyl ester

(Z)-3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Hexadecafluoro-dec-2-enoic acid ethyl ester

(Z)-4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Pentadecafluoro-3-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octylamino)-dec-2-enoic acid ethyl ester
693825-90-0

(Z)-4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Pentadecafluoro-3-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octylamino)-dec-2-enoic acid ethyl ester

Conditions
ConditionsYield
With triethylamine In diethyl ether for 48h; Heating;79%
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

Dicyclohexyl-oxiranylmethyl-amine
27110-25-4

Dicyclohexyl-oxiranylmethyl-amine

1-Dicyclohexylamino-3-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octylamino)-propan-2-ol

1-Dicyclohexylamino-3-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octylamino)-propan-2-ol

Conditions
ConditionsYield
at 30 - 40℃; for 16h;78%
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

Ethyl 2-bromopropionate
535-11-5, 41978-69-2

Ethyl 2-bromopropionate

2-(3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-octylamino)-propionic acid ethyl ester
142349-75-5

2-(3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-octylamino)-propionic acid ethyl ester

Conditions
ConditionsYield
With N-benzyl-N,N,N-triethylammonium chloride; potassium carbonate In acetonitrile at 70℃;78%
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

2-propenamide
79-06-1

2-propenamide

3-(3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-octylamino)-propionamide
185798-63-4

3-(3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-octylamino)-propionamide

Conditions
ConditionsYield
In ethanol for 96h; Ambient temperature;78%
2-[2-(2-iodoethoxy)ethoxy]ethanol
62573-16-4

2-[2-(2-iodoethoxy)ethoxy]ethanol

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

2-(2-{2-[{2-[2-(2-Hydroxy-ethoxy)-ethoxy]-ethyl}-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-amino]-ethoxy}-ethoxy)-ethanol

2-(2-{2-[{2-[2-(2-Hydroxy-ethoxy)-ethoxy]-ethyl}-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-amino]-ethoxy}-ethoxy)-ethanol

Conditions
ConditionsYield
With sodium carbonate In acetonitrile77%
Boc-Lys(Z)-OH
2389-45-9

Boc-Lys(Z)-OH

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

N-(tert-butyloxycarbonyl)-Nε-(benzyloxycarbonyl)-L-lysinyl-1H,1H,2H,2H-perfluorooctylamide
887760-22-7

N-(tert-butyloxycarbonyl)-Nε-(benzyloxycarbonyl)-L-lysinyl-1H,1H,2H,2H-perfluorooctylamide

Conditions
ConditionsYield
With benzotriazol-1-ol; dicyclohexyl-carbodiimide In dichloromethane at 20℃; for 24h;77%
3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine
30556-86-6

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylamine

ethyl bromoacetate
105-36-2

ethyl bromoacetate

(3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-octylamino)-acetic acid ethyl ester
142349-74-4

(3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-octylamino)-acetic acid ethyl ester

Conditions
ConditionsYield
With N-benzyl-N,N,N-triethylammonium chloride; potassium carbonate In acetonitrile at 70℃;76%

30556-86-6Relevant articles and documents

Convenient synthesis of monodisperse fluorinated nonionic surfactants containing two hydrophilic hydroxylated moieties

Guittard, Frederic,De Givenchy, Elisabeth Taffin,Szoenyi, Francois,Cambon, Aime

, p. 7863 - 7866 (1995)

New fluorinated nonionic surfactants containing two monodisperse oligo(oxyethylene) tails and having a hydroxyl group in the terminal position were easily obtained, with good yields, a purity higher than 95%, a high solubility in water and show interesting surface properties for their physicochemical application: low surface tensions and noteworthy critical micelle concentrations.

Nouvelles methodes de preparation des 2-F-alkylethylamines

Szoenyi, F.,Guennouni, F.,Cambon, A.

, p. 85 - 92 (1991)

2-F-Alkylethylamines are difficult to obtain on the laboratory scale and their preparation without the formation of secondary products has never been reported.In this work we demonstrate that it is possible to obtain these compounds univocally and with easy to use methods.The spectral data of these compounds are reported for the first time.

Synthese des 2-F-alkylethylamines: optimisation de l'obtention des azotures de 2-F-alkyletyle et de leur reduction en amines

Trabelsi, H.,Szoenyi, F.,Michelangeli, N.,Cambon, A.

, p. 115 - 118 (1994)

2-F-Alkylethylamines are very important intermediates in organic fluorine chemistry.In this work, it has been demonstrated that it is possible to combine the advantages of two techniques, i.e. phase-transfer catalysis and the use of water as a dispersing medium, in the reduction of 2-F-alkylethyl azides, and hence simplify significantly the synthesis of such amines from 2-F-alkylethyl iodides.

Light-fluorous TEMPO: reagent, spin trap and stable free radical

Dobbs, Adrian P.,Jones, Peter,Penny, Mark J.,Rigby, Stephen E.

supporting information; experimental part, p. 5271 - 5277 (2009/11/30)

The synthesis of two light-fluorous TEMPO derivatives is reported, along with their fluorous-organic solvent partition coefficients and their ESR spectra. Applications of the fluorous-TEMPO reagents in oxidation reactions and as radical traps are discussed.

Novel light-fluorous TEMPO reagents and their application in oxidation reactions

Dobbs, Adrian P.,Penny, Mark J.,Jones, Peter

scheme or table, p. 6955 - 6958 (2009/04/07)

The synthesis of two light-fluorous TEMPO derivatives is reported, along with their application in oxidation reactions.

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