307930-64-9

Basic information

• Product Name: (((perfluorophenyl)methylene)bis(1H-pyrrole-5,2-diyl))bis((perfluorophenyl)methanone)
• Synonyms: (((perfluorophenyl)methylene)bis(1H-pyrrole-5,2-diyl))bis((perfluorophenyl)methanone)
• CAS NO: 307930-64-9
• Molecular Weight: 700.363
• Mol File: 307930-64-9.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: (((perfluorophenyl)methylene)bis(1H-pyrrole-5,2-diyl))bis((perfluorophenyl)methanone)(CAS DataBase Reference)
• NIST Chemistry Reference: (((perfluorophenyl)methylene)bis(1H-pyrrole-5,2-diyl))bis((perfluorophenyl)methanone)(307930-64-9)
• EPA Substance Registry System: (((perfluorophenyl)methylene)bis(1H-pyrrole-5,2-diyl))bis((perfluorophenyl)methanone)(307930-64-9)

Safety Data

• Hazardous Substances Data: 307930-64-9(Hazardous Substances Data)

Upstream product

• 653-37-2 perfluorobenzaldehyde 
• 2251-50-5 pentafluorobenzoylchloride 
• 167482-91-9 5-(pentafluorophenyl)dipyrromethane 

Downstream Products

• 868654-38-0 5,10,15-tris(pentafluorophenyl)porphyrinatozinc(II) 
• 868654-38-0 5,10,15-tris(pentafluorophenyl)porphyrinatozinc(II) 
• 847866-59-5 dibutyl[5,10-dihydro-1,9-bis(pentafluorobenzoyl)-5-pentafluorophenyldipyrrinato] tin(IV) 
• 238402-21-6 5,10,15-tris(2,3,4,5,6-pentafluorophenyl)corrole 
• 925900-28-3 5,5'-((perfluorophenyl)methylene)bis(2-((perfluorophenyl)(1H-pyrrol-2-yl)methyl)-1H-pyrrole) 
• 680575-57-9 1,9-bis(pentafluorophenylhydroxymethyl)-5-(pentafluorophenyl)dipyrromethane 

Relevant articles and documents

Enantiotopos-selective C-H oxygenation catalyzed by a supramolecular ruthenium complex

Spirocyclic oxindoles undergo an enantioselective oxygenation reaction (nine examples; e.r. up to 97:3) upon catalysis by a chiral ruthenium porphyrin complex (1 mol%). The catalyst exhibits a lactam ring, which is responsible for substrate association through hydrogen bonds, and an active ruthenium center, which is in a defined spatial relationship to the oxygenation substrate. DFT calculations illustrate the perfect alignment of the active site with the reactive C-H bond and suggest-in line with the kinetic isotope effect-an oxygen rebound mechanism for the reaction.

Synthesis of A2B6-type [36]octaphyrins: Copper(II)-metalation-induced fragmentation reactions to porphyrins and N-fusion reactions of meso-(3-thienyl) substituents

5,10,15-Tris(pentafluorophenyl)tetrapyrromethane was efficiently prepared through a route involving stepwise diaroylation of 5- pentafluorophenyldipyrromethane. A2B6-type [36]octaphyrins were prepared by the cross condensation of the

Hydrogen generation by hangman metalloporphyrins

A cobalt(II) hangman porphyrin with a xanthene backbone and a carboxylic acid hanging group catalyzes the electrochemical production of hydrogen from benzoic and tosic acid in acetonitrile solutions. We show that CoIIH is exclusively involved i