925900-28-3

Basic information

• Product Name: 5,5'-((perfluorophenyl)methylene)bis(2-((perfluorophenyl)(1H-pyrrol-2-yl)methyl)-1H-pyrrole)
• Synonyms: 5,5'-((perfluorophenyl)methylene)bis(2-((perfluorophenyl)(1H-pyrrol-2-yl)methyl)-1H-pyrrole)
• CAS NO: 925900-28-3
• Molecular Weight: 802.545
• Mol File: 925900-28-3.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 5,5'-((perfluorophenyl)methylene)bis(2-((perfluorophenyl)(1H-pyrrol-2-yl)methyl)-1H-pyrrole)(CAS DataBase Reference)
• NIST Chemistry Reference: 5,5'-((perfluorophenyl)methylene)bis(2-((perfluorophenyl)(1H-pyrrol-2-yl)methyl)-1H-pyrrole)(925900-28-3)
• EPA Substance Registry System: 5,5'-((perfluorophenyl)methylene)bis(2-((perfluorophenyl)(1H-pyrrol-2-yl)methyl)-1H-pyrrole)(925900-28-3)

Safety Data

• Hazardous Substances Data: 925900-28-3(Hazardous Substances Data)

Upstream product

• 167482-91-9 5-(pentafluorophenyl)dipyrromethane 
• 109-97-7 pyrrole 
• 653-37-2 perfluorobenzaldehyde 
• 2251-50-5 pentafluorobenzoylchloride 
• 307930-64-9 (((perfluorophenyl)methylene)bis(1H-pyrrole-5,2-diyl))bis((perfluorophenyl)methanone) 
• 680575-57-9 1,9-bis(pentafluorophenylhydroxymethyl)-5-(pentafluorophenyl)dipyrromethane 

Downstream Products

• 238402-21-6 5,10,15-tris(2,3,4,5,6-pentafluorophenyl)corrole 
• 238402-21-6 5,10,15-tris(pentafluorophenyl)corrole 
• 262280-86-4 [(5,10,15-tris(pentafluorophenyl)corrolate)copper(III)] 

Relevant articles and documents

Straightforward Syntheses That Avoid Scrambling of meso-Substituted [28]Hexaphyrins

A two-step synthesis of meso-substituted [28]hexaphyrins in an aqueous medium was developed and optimized, and scrambling processes are avoided despite the use of a high acid concentration. The efficiency of this procedure relies on the nature of the star

Synthesis of meso-substituted corroles and porphyrins using iodine as a catalyst

Abstract: Different types of corroles and porphyrins are synthesized from substituted aldehydes and pyrrole. The current synthetic method involves iodine as catalyst and proceeds at room temperature itself. By varying the amounts of reactants (i.e., pyrrole and aldehydes), the corrole and porphyrins were obtained in good to excellent yields. These products were characterized by 1H-NMR, UV-visible, and HRMS techniques. The reaction approach utilizes the readily available pyrrole and substituted aldehydes as starting materials and makes this reaction highly attractive in diversity-oriented synthesis. Graphic abstract: Different types of porphyrins and corroles are synthesized from substituted aldehydes and pyrrole using iodine as a catalyst and the reaction proceeds at room temperature itself. By varying the amount of reactants (i.e. pyrrole and aldehydes), the porphyrins and corroles are obtained in good to excellent yields.[Figure not available: see fulltext.]

Control of oligomerization and oxidation steps in the synthesis of tris(pentafluorophenyl)corrole

The mechanistic features of oligomerization and oxidative cyclization steps in the synthesis of tris(pentafluorophenyl)corrole (1) have been thoroughly studied. Separation of the intermediates by preparative HPLC and analysis by NMR spectroscopy and high