30905-13-6

Basic information

• Product Name: 4-biphenylylphenyldiazomethane
• Synonyms: 4-biphenylylphenyldiazomethane
• CAS NO: 30905-13-6
• Molecular Weight: 270.334
• Mol File: 30905-13-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4-biphenylylphenyldiazomethane(CAS DataBase Reference)
• NIST Chemistry Reference: 4-biphenylylphenyldiazomethane(30905-13-6)
• EPA Substance Registry System: 4-biphenylylphenyldiazomethane(30905-13-6)

Safety Data

• Hazardous Substances Data: 30905-13-6(Hazardous Substances Data)

Upstream product

• 116495-92-2 4-phenyl-benzophenone-hydrazone 

Downstream Products

• 32566-91-9 N-([1,1'-biphenyl]-4-yl(phenyl)methyl)aniline 
• 1638192-41-2 4-(2,2-difluoro-1-phenylvinyl)-1,1'-biphenyl 
• 982-46-7 4-(1,3-diphenylpropa-1,2-dien-1-yl)-1,1'-biphenyl 
• 83989-81-5 7-Biphenyl-4-yl-1,3-dioxo-2,7-diphenyl-2,3-dihydro-1H,7H-pyrazolo[1,2-a][1,2,4]triazole-5,6-dicarboxylic acid dimethyl ester 
• 2128-93-0 biphenyl-4-yl-phenyl-methanone 
• 7598-80-3 4-phenylbenzhydrol 
• 745-36-8 4-benzhydryl-1,1'-biphenyl 
• 87-87-6 2,3,5,6-tetrachlorobenzene-1,4-diol 
• 14845-83-1 4-biphenylphenylcarbene 
• 82820-04-0 C₂₇H₁₉N₃O₂ 
• 74399-90-9 1,1,1,2,2,3-hexachloro-3-(4'-biphenylyl)-3-phenyl propane 
• 121815-42-7 2-biphenyl-4-yl-2-phenyl-phenanthro[9,10-d][1,3]dioxole 
• 103268-58-2 1-biphenyl-4-yl-2,2-bis-(4-dimethylamino-phenyl)-1-phenyl-ethene 
• 103266-97-3 9-(4-phenyl-benzhydrylidene)-xanthene 

Relevant articles and documents

Copper-Mediated Cross-Coupling of Diazo Compounds with Sulfinates

A copper-mediated cross-coupling reaction between a diazo compound and a sodium alkane(arene)sulfinate gives a sulfone as the product. This reaction proceeds under mild conditions and features excellent functional group compatibility. A wide range of sodium alkane(arene)sulfinates were successfully applied in this chemistry. Mechanistic studies revealed that the overall reaction efficiency of the sulfinates was in line with their nucleophilicity in this reaction.

Cu(I)-catalyzed coupling of diaryldiazomethanes with terminal alkynes: An efficient synthesis of tri-aryl-substituted allenes

A highly efficient method for the synthesis of tri-aryl-substituted allenes has been developed through Cu(I)-catalyzed coupling of diaryldiazomethanes with terminal alkynes. The reaction is under mild conditions and uses simple and inexpensive CuI as the catalyst. Mechanistically, the reaction follows a pathway involving Cu(I) carbene migratory insertion.