313344-25-1Relevant articles and documents
Solid phase Diels-Alder/retro Diels-Alder reactions. A new method for traceless linker strategy
Blanco,Bloch,Bugnet,Deloisy
, p. 7875 - 7878 (2000)
A resin-bound furan has been efficiently synthesized from Merrifield resin. This new polymer reacts with an acetylenic dienophile to afford a thermally stable Diels-Alder adduct. Transformation of the adduct by Michael reaction with thiophenol has allowed an easy retro Diels-Alder reaction. This 'safety-catch' procedure leads to the formation of a chemically and stereochemically pure alkene and to the regeneration of the polymer-bound furan. (C) 2000 Elsevier Science Ltd.
Stereoselective 1,3-dipolar cycloaddition of a maleate derivative with azomethine ylides derived from α-amino esters: Synthesis of 3-pyrrolines
Soret, Adrien,Guillot, Régis,Rousseau, Gérard,Blanco, Luis,Deloisy, Sandrine
, p. 1284 - 1288 (2008/02/07)
A new preparation of 3-pyrrolines is described by [3+2] cycloadditions of N-metalated azomethine ylides derived from α-amino esters with a dimethyl 7-oxabicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylate derivative, followed by retro-Diels-Alder reactions. T