31749-10-7

Basic information

• Product Name: 3,4-DIMETHOXYPHENYL-(2-PYRIDYL)METHANOL
• Synonyms: 3,4-DIMETHOXYPHENYL-(2-PYRIDYL)METHANOL
• CAS NO: 31749-10-7
• Molecular Formula: C₁₄H₁₅NO₃
• Molecular Weight: 245.27
• Mol File: 31749-10-7.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3,4-DIMETHOXYPHENYL-(2-PYRIDYL)METHANOL(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4-DIMETHOXYPHENYL-(2-PYRIDYL)METHANOL(31749-10-7)
• EPA Substance Registry System: 3,4-DIMETHOXYPHENYL-(2-PYRIDYL)METHANOL(31749-10-7)

Safety Data

• Hazardous Substances Data: 31749-10-7(Hazardous Substances Data)

Upstream product

• 98-98-6 2-Picolinic acid 
• 120-14-9 3,4-dimethoxy-benzaldehyde 
• 499-83-2 Pyridine-2,6-dicarboxylic acid 
• 1121-60-4 pyridine-2-carbaldehyde 
• 91-16-7 1,2-dimethoxybenzene 
• 109-04-6 2-bromo-pyridine 

Downstream Products

• 102458-70-8 2-(3,4-dimethoxybenzyl)piperidine 
• 27693-42-1 (3,4-dimethoxyphenyl)(pyridin-2-yl)methanone 
• 100710-88-1 2-(3,4-dimethoxybenzyl)pyridine 
• 6495-96-1 8,9-dimethoxy-4,6,11,11a-tetrahydro-1H-benzoquinolizine 

Relevant articles and documents

Cobalt(II)-based Metalloradical Activation of 2-(Diazomethyl)pyridines for Radical Transannulation and Cyclopropanation

A new catalytic method for the denitrogenative transannulation/cyclopropanation of in-situ-generated 2-(diazomethyl)pyridines is described using a cobalt-catalyzed radical-activation mechanism. The method takes advantage of the inherent properties of a CoIII-carbene radical intermediate and is the first report of denitrogenative transannulation/cyclopropanation by a radical-activation mechanism, which is supported by various control experiments. The synthetic benefits of the metalloradical approach are showcased with a short total synthesis of (±)-monomorine.

Aroylcrownethers

Aroylcrownethers are complexing agents for metals, dispersing agents for carbon black and preferred ones are antiviral agents. Examplary is 4'-benzoylbenzo-18-crown-6 of the formula STR1