317802-17-8Relevant articles and documents
On the way to α-methyl-α-amino acids; unusual elimination-addition in 3,3-disubstituted 1,4-benzodiazepin-2-ones and inversion of enantioselectivity in the lipase catalyzed acetylation
Avdagic, Amir,Sunjic, Vitomir
, p. 743 - 753 (2007/10/03)
(-)-3-Methanesulfoxymethyl-3-acetoxoymethyl-7-chloro-5-phenyl-1,4- benzodiazepin-2-one, (-)-2, reacts with ethanethiol in the presence of a strong base affording racemic elimination-addition product 3-ethylthiomethyl-7-chloro-5-phenyl-1,4-benzodiazepin-2-