318-69-4Relevant articles and documents
Thiolate-Initiated Synthesis of Dibenzothiophenes from 2,2′-Bis(methylthio)-1,1′-Biaryl Derivatives through Cleavage of Two Carbon-Sulfur Bonds
Chatani, Naoto,Kawashima, Yuki,Kodama, Takuya,Masuya, Yoshihiro,Tobisu, Mamoru
, p. 1995 - 1999 (2019/10/22)
A catalytic reaction involving the cleavage of two carbon-sulfur bonds in 2,2′-bis(methylthio)-1,1′-biaryl derivatives is reported. This reaction does not require a transition-metal catalyst and is promoted by a thiolate anion. Notably, based on DFT calculations, the product-forming cyclization step is shown to proceed through a concerted nucleophilic aromatic substitution (CS N Ar) mechanism.
CARBAZOLE-CONTAINING MATERIALS IN PHOSPHORESCENT LIGHT EMITTING DIODES
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, (2009/06/27)
Carbazole-containing compounds are provided. In particular, the compounds are oligocarbazole-containing compounds having an unsymmetrical structure. The compounds may be useful in organic light emitting devices, in particular as hosts in the emissive layer of such devices.
New entry to benzo[b]thieno[2,3-b]- and benzo[b]thieno-[3,2-b]-pyridines using 2- and 3-azidobenzo[b]thiophene as the nitrogen precursors
Degl'Innocenti, Alessandro,Funicello, Maria,Scafato, Patrizia,Spagnolo, Piero,Zanirato, Paolo
, p. 2561 - 2563 (2007/10/03)
N-(3-Benzo[b]thienyl)- and N-(2-benzo[b]thienyl)-iminotriphenylphosphorane - prepared from the corresponding azidobenzo[b]thiophenes - react with α,β-unsaturated aldehydes under mild conditions to give directly benzo-[b]thieno[3,2-b]- and benzo[b]thieno[2