31896-75-0

Basic information

• Product Name: 1,1'-dimethyl-3,3'methylenedi-indole
• Synonyms: 1,1'-dimethyl-3,3'methylenedi-indole
• CAS NO: 31896-75-0
• Molecular Formula: C₁₉H₁₈N₂
• Molecular Weight: 274
• Mol File: 31896-75-0.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1,1'-dimethyl-3,3'methylenedi-indole(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1'-dimethyl-3,3'methylenedi-indole(31896-75-0)
• EPA Substance Registry System: 1,1'-dimethyl-3,3'methylenedi-indole(31896-75-0)

Safety Data

• Hazardous Substances Data: 31896-75-0(Hazardous Substances Data)

Upstream product

• 19012-03-4 N-methyl-3-formylindole 
• 1912-48-7 2-(1-methyl-1H-indol-3-yl)acetic acid 
• 603-76-9 1-methylindole 
• 50-00-0 formaldehyd 
• 106-47-8 4-chloro-aniline 
• 120-72-9 indole 
• 1073-67-2 4-vinylbenzyl chloride 
• 124-38-9 carbon dioxide 
• 121-69-7 N,N-dimethyl-aniline 

Downstream Products

• 61844-15-3 N-methylindole-3-azo-(4'-nitrobenzene) 
• 61844-16-4 1-methyl-2-(1'-methylindol-3'-ylmethyl)-3-(p-nitrophenylazo)indole 
• 318-54-7 2,2,2-trifluoro-1-(1-methyl-1H-indol-3-yl)ethan-1-one 

Relevant articles and documents

Fe-S Catalyst Generated in Situ from Fe(III)- And S3?--Promoted Aerobic Oxidation of Terminal Alkenes

An iron-sulfur complex formed by the simple mixture of FeCl3 with S3?- generated in situ from K2S is developed and applied to selective aerobic oxidation of terminal alkenes. The reaction was carried out under an atmosphere of O2 (balloon) and could proceed on a gram scale, expanding the application of S3?- in organic synthesis. This study also encourages us to explore the application of an Fe-S catalyst in organic reactions.

C-Methylenation of anilines and indoles with CO2and hydrosilane using a pentanuclear zinc complex catalyst

The one-stepC-methylenation of anilines and indoles with CO2and phenylsilane was catalyzed by a pentanuclear ZnIIcomplex to give diarylmethanesviageminal C-H and C-C bond formation. It is proposed that the zinc-hydride complex generatedin situis a catalytically active species and that bis(silyl)acetal is a key intermediate. When aniline was used as a substrate, both theC-methylenation andN-methylation proceeded.

DYE-SENSITIZED PHOTOOXIDATION OF 1-METHYLINDOLYL-3-ACETIC ACID

The structure of the products constituting the complex mixture afforded by the entitled reaction is similar to that proceeding from the N-unmethylated acid and supports the presumed mechanistic analogy with the enzymatic oxidation.