330-80-3Relevant articles and documents
Enantioselective Suzuki cross-couplings of unactivated 1-fluoro-1-haloalkanes: Synthesis of chiral β-, γ-, δ-, and ε-fluoroalkanes
Jiang, Xiaojian,Gandelman, Mark
supporting information, p. 2542 - 2547 (2015/03/04)
The incorporation of fluorine atom into a stereogenic center is a highly challenging transformation with current methodologies offering access mainly to chiral α- and β-fluoroalkanes. In this article, the development of a novel general approach to constru
Efficient synthesis of secondary alkyl fluorides via suzuki cross-coupling reaction of 1-halo-1-fluoroalkanes
Jiang, Xiaojian,Sakthivel, Sekarpandi,Kulbitski, Kseniya,Nisnevich, Gennady,Gandelman, Mark
supporting information, p. 9548 - 9551 (2014/07/22)
Organofluorine compounds have found extensive applications in various areas of science. Consequently, the development of new efficient and selective methods for their synthesis is an important goal in organic chemistry. Here, we present the first Suzuki c
Simple procedure for preparation of α-fluoro esters by fluorination of ester enol silyl ethers with perchloryl fluoride
Fujisawa, Hidehito,Takeuchi, Yoshio
, p. 173 - 176 (2007/10/03)
Fluorination of ester enol silyl ethers in THF at room temperature using diluted perchloryl fluoride (FClO3) in the presence of ca. 0.5M eq. of t-BuNH2 as an additive produced the corresponding α-fluoro esters in over 80% yields.
