330825-67-7Relevant articles and documents
Asymmetric palladium-catalyzed hydrosilylation of styrenes using efficient chiral spiro phosphoramidite ligands
Guo, Xun-Xiang,Xie, Jian-Hua,Hou, Guo-Hua,Shi, Wen-Jian,Wang, Li-Xin,Zhou, Qi-Lin
, p. 2231 - 2234 (2007/10/03)
Asymmetric hydrosilylation of styrene derivatives with trichlorosilane in the presence of palladium complexes of chiral spiro phosphoramidites provided 1-aryl-1-silylalkanes as single regioisomers in high yields, which have been oxidized with hydrogen peroxide to give the corresponding chiral alcohols in up to 99.1% ee.