33104-16-4

Basic information

• Product Name: Benzene, 1-chloro-4-(dichloromethoxy)-
• CAS NO: 33104-16-4
• Molecular Formula: C7H5Cl3O
• Molecular Weight: 211.475
• Mol File: 33104-16-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 1-chloro-4-(dichloromethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-chloro-4-(dichloromethoxy)-(33104-16-4)
• EPA Substance Registry System: Benzene, 1-chloro-4-(dichloromethoxy)-(33104-16-4)

Safety Data

• Hazardous Substances Data: 33104-16-4(Hazardous Substances Data)

Upstream product

• 623-12-1 4-chloromethoxybenzene 
• 67-66-3 chloroform 
• 106-48-9 4-chloro-phenol 
• 21151-56-4 p-chlorophenoxymethyl chloride 

Downstream Products

• 81932-03-8 4-chloro-α,α-difluoroanisole 

Relevant articles and documents

Formation of Dichloromethyl Phenyl Ethers as Major Products in Photo-Reimer-Tiemann Reaction without Base

Photolysis of phenols 1a-d in chloroform or carbon tetrachloride afforded the corresponding di- or trichloromethyl phenyl ethers (2a-d or 6a-d, respectively).In chloroform, hydroxybenzaldehydes 4a-d or 5 and phenyl formates 3a-d were obtained as minor photoproducts.In carbon tetrachloride, traces of salicyloyl chloride (7), phenyl salicylate (8) and phenyl p-hydroxybenzoate (9) were detected starting from the parent phenol (1a).The obtained results agree with the involvement of an electron transfer mechanism.