332124-25-1Relevant articles and documents
CuSO4-Catalyzed Tandem C(sp3)-H Insertion Cyclization of Toluenes with Isonitriles to Form Indoles
Shan, Xiang-Huan,Wang, Mei-Mei,Tie, Lin,Qu, Jian-Ping,Kang, Yan-Biao
supporting information, p. 357 - 360 (2020/01/31)
A CuSO4-catalyzed tandem benzylic C-H insertion cyclization of toluene derivatives and isonitriles is described. The naturally abundant salt CuSO4 serves as a low-cost ligand-free redox catalyst. This reaction provides a practical mo
Phenanthroline- tBuOK Promoted Intramolecular C-H Arylation of Indoles with ArI under Transition-Metal-Free Conditions
Shan, Xiang-Huan,Yang, Bo,Zheng, Hong-Xing,Qu, Jian-Ping,Kang, Yan-Biao
supporting information, p. 7898 - 7901 (2019/01/04)
The first example of phenanthroline-tBuOK promoted intramolecular radical C-H arylation of N-(2-iodobenzyl)indoles without involvement of transition metals has been developed. A variety of substituted 6H-isoindolo [2, 1-a] indoles were prepared by a simple and efficient intramolecular cyclization using 1,10-phenanthroline in the presence of potassium tert-butoxide and chlorobenzene. This strategy provides a fast and versatile access to isoindolo[2,1-a]indole derivatives for the synthesis of pharmaceuticals and organic electroluminescent (EL) materials.
A convenient route to 2-hydroxy- and 2,15-dihydroxyhexahelicene
Teply, Filip,Stara, Irena G.,Stary, Ivo,Kollarovic, Adrian,Lustinec, Daniel,Krausova, Zuzana,Saman, David,Fiedler, Pavel
, p. 4244 - 4250 (2008/03/14)
2-Hydroxy- and 2,15-dihydroxyhexahelicene were synthesised from simple benzene and naphthalene building blocks by intramolecular Co1- or Ni0-catalysed [2+2+2] cycloisomerisation of CH3O- substituted aromatic triynes. This
