335164-94-8

Basic information

• Product Name: N-[(1,1-dimethylethoxy)carbonyl]-N-[(phenylseleno)methyl]glycinal
• Synonyms: N-[(1,1-dimethylethoxy)carbonyl]-N-[(phenylseleno)methyl]glycinal
• CAS NO: 335164-94-8
• Molecular Weight: 328.27
• Mol File: 335164-94-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-[(1,1-dimethylethoxy)carbonyl]-N-[(phenylseleno)methyl]glycinal(CAS DataBase Reference)
• NIST Chemistry Reference: N-[(1,1-dimethylethoxy)carbonyl]-N-[(phenylseleno)methyl]glycinal(335164-94-8)
• EPA Substance Registry System: N-[(1,1-dimethylethoxy)carbonyl]-N-[(phenylseleno)methyl]glycinal(335164-94-8)

Safety Data

• Hazardous Substances Data: 335164-94-8(Hazardous Substances Data)

Upstream product

• 23974-72-3 sodium phenylselenide 
• 172096-95-6 1,1-dimethylethyl 5-oxo-3-oxazolidinecarboxylate 
• 335164-93-7 methyl N-[(1,1-dimethylethoxy)carbonyl]-N-[(phenylseleno)methyl]glycinate 

Downstream Products

• 181134-89-4 1,1-dimethylethyl [2-[[bis(1,1-dimethylethyl)silyl]oxy]-4-phenyl-3-butynyl][(phenylseleno)methyl]carbamate 
• 335165-20-3 1,1-dimethylethyl (2-hydroxy-3-butynyl)[(phenylseleno)methyl]carbamate 
• 335165-19-0 1,1-dimethylethyl (2-hydroxy-4-trimethylsilyl-3-butynyl)[(phenylseleno)methyl]carbamate 
• 335164-95-9 1,1-dimethylethyl (2-hydroxy-4-phenyl-3-butynyl)[(phenylseleno)methyl]carbamate 

Relevant articles and documents

Preparation of polycyclic systems by sequential 5-exo-digonal radical cyclization, 1,5-hydrogen transfer from silicon, and 5-endo-trigonal cyclization

Radicals of type 1 undergo 5-exo diagonal cyclization, and the resulting vinyl radical abstracts hydrogen from silicon to afford a silicon-centered radical. This radical closes in a 5-endo trigonal manner to generate radicals of type 4, which are reduced