335165-19-0

Basic information

• Product Name: 1,1-dimethylethyl (2-hydroxy-4-trimethylsilyl-3-butynyl)[(phenylseleno)methyl]carbamate
• Synonyms: 1,1-dimethylethyl (2-hydroxy-4-trimethylsilyl-3-butynyl)[(phenylseleno)methyl]carbamate
• CAS NO: 335165-19-0
• Molecular Weight: 426.49
• Mol File: 335165-19-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,1-dimethylethyl (2-hydroxy-4-trimethylsilyl-3-butynyl)[(phenylseleno)methyl]carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1-dimethylethyl (2-hydroxy-4-trimethylsilyl-3-butynyl)[(phenylseleno)methyl]carbamate(335165-19-0)
• EPA Substance Registry System: 1,1-dimethylethyl (2-hydroxy-4-trimethylsilyl-3-butynyl)[(phenylseleno)methyl]carbamate(335165-19-0)

Safety Data

• Hazardous Substances Data: 335165-19-0(Hazardous Substances Data)

Upstream product

• 335164-93-7 methyl N-[(1,1-dimethylethoxy)carbonyl]-N-[(phenylseleno)methyl]glycinate 
• 172096-95-6 1,1-dimethylethyl 5-oxo-3-oxazolidinecarboxylate 
• 335164-94-8 N-[(1,1-dimethylethoxy)carbonyl]-N-[(phenylseleno)methyl]glycinal 
• 1066-54-2 trimethylsilylacetylene 

Downstream Products

• 335165-20-3 1,1-dimethylethyl (2-hydroxy-3-butynyl)[(phenylseleno)methyl]carbamate 

Relevant articles and documents

Preparation of polycyclic systems by sequential 5-exo-digonal radical cyclization, 1,5-hydrogen transfer from silicon, and 5-endo-trigonal cyclization

Radicals of type 1 undergo 5-exo diagonal cyclization, and the resulting vinyl radical abstracts hydrogen from silicon to afford a silicon-centered radical. This radical closes in a 5-endo trigonal manner to generate radicals of type 4, which are reduced