335596-12-8Relevant articles and documents
Oxidative fragmentation of bicyclic hydroxy silanes and stannanes: a strategy for the stereoselective synthesis of kainoids
Clayden, Jonathan,Hebditch, Katherine R.,Read, Benjamin,Helliwell, Madeleine
, p. 8550 - 8553 (2008/09/17)
The addition of tin or silicon nucleophiles to bicyclic enones generated by dearomatising cyclisation gives stannanes and silanes stereoselectively. These compounds may be fragmented under oxidative conditions to generate substituted pyrrolidines bearing