33650-06-5

Basic information

• Product Name: sodium salt of carbazole
• Synonyms: sodium salt of carbazole
• CAS NO: 33650-06-5
• Molecular Weight: 189.192
• Mol File: 33650-06-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: sodium salt of carbazole(CAS DataBase Reference)
• NIST Chemistry Reference: sodium salt of carbazole(33650-06-5)
• EPA Substance Registry System: sodium salt of carbazole(33650-06-5)

Safety Data

• Hazardous Substances Data: 33650-06-5(Hazardous Substances Data)

Upstream product

• 86-74-8 9H-carbazole 

Downstream Products

• 524-80-1 9-carbazolylacetic acid 
• 124782-50-9 (C₆H₅)2Sb(NC₆H₄C₆H₄) 
• 6209-23-0 2-(9H-carbazole-9-yl) acetic acid ethyl ester 
• 23866-67-3 9-(2-pyridyl)carbazole 

Relevant articles and documents

An Efficient Synthesis of N-(Hetero)arylcarbazoles: Palladium-Catalyzed Coupling Reaction between (Hetero)aryl Chlorides and N-Carbazolylmagnesium Chloride

An efficient method for the synthesis of N-(hetero)arylcarbazoles, useful compounds for functional materials, is reported. Various (hetero)aryl chlorides reacted with N-carbazolylmagnesium chloride in the presence of a palladium catalyst (0.05 to 0.2 mol%) prepared from allylpalladium(II) chloride dimer {[PdCl(allyl)]2} and di-tert-butyl(2,2-diphenyl-1-methylcyclopropan-1-yl)phosphine (cBRIDP) under mild conditions (110°C) in a short period of time (15 min to 2 h) to give N-(hetero)arylcarbazoles in high yields. The reactions of bromochlorobenzenes proceeded in favour of the bromo group to afford N-(chlorophenyl)carbazoles in a highly selective manner. Functional materials for use in organic light-emitting diodes, such as mCP, 26mcPy, CBP and TCB, were also obtained in high yields within 15 min by the reaction of (hetero)aryl polyhalides. Optimization of the reaction conditions and a postulated catalytic cycle for the reaction are also discussed.