33715-53-6

Basic information

• Product Name: p-(Fluorophenyl)triethoxysilane
• Synonyms: p-(Fluorophenyl)triethoxysilane
• CAS NO: 33715-53-6
• Molecular Formula: C₁₂H₁₉FO₃Si
• Molecular Weight: 258.36
• Mol File: 33715-53-6.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: p-(Fluorophenyl)triethoxysilane(CAS DataBase Reference)
• NIST Chemistry Reference: p-(Fluorophenyl)triethoxysilane(33715-53-6)
• EPA Substance Registry System: p-(Fluorophenyl)triethoxysilane(33715-53-6)

Safety Data

• Hazardous Substances Data: 33715-53-6(Hazardous Substances Data)

Upstream product

• 78-10-4 tetraethoxy orthosilicate 
• 352-13-6 4-flourophenylmagnesium bromide 
• 460-00-4 1-Bromo-4-fluorobenzene 

Downstream Products

• 13272-84-9 (4-fluorophenyl)silane 
• 1186241-75-7 N-(3-(4-fluorophenyl)-2H-chromen-4-yl)acetamide 
• 397-54-6 2-(4-fluorophenyl)benzoxazole 
• 398-23-2 4,4'-difluorobiphenyl 
• 1582806-71-0 (S)-3-(4-fluorophenyl)-2-phthalimido-N-(2,3,5,6-tetrafluoro-4-(trifluoromethyl)phenyl)propanamide 
• 1341224-06-3 dodecyl 4-fluorobenzenethioate 
• 345-83-5 4-fluorobenzophenone 
• 130754-17-5 ethyl 2-fluoro-2-(4-fluorophenyl)acetate 
• 310-40-7 diethyl (4-fluorophenyl)phosphonate 
• 324-74-3 4-fluoro-biphenyl 
• 4280-40-4 4-(4-fluorophenyl)morpholine 
• 1057224-07-3 3-(4-fluorophenyl)-1-methylquinoxalin-2(1H)-one 
• 88229-29-2 N,N-dibenzyl-4-fluorobenzamide 

Relevant articles and documents

Rhodium(III)-Catalyzed Direct C-H Arylation of Various Acyclic Enamides with Arylsilanes

The stereoselective β-C(sp2)-H arylation of various acyclic enamides with arylsilanes via Rh(III)-catalyzed cross-coupling reaction was illustrated. The methodology was characterized by extraordinary efficacy and stereoselectivity, a wide scope of substrates, good functional group tolerance, and the adoption of environmentally friendly arylsilanes. The utility of this present method was evidenced by the gram-scale synthesis and further elaboration of the product. In addition, Rh(III)-catalyzed C-H activation is considered to be the critical step in the reaction mechanism.

Ligand-promoted oxidative cross-coupling of aryl boronic acids and aryl silanes by palladium catalysis

The first cross-coupling reaction between aryl silanes and aryl boronic acids is described. This transformation represents one of the very few examples of coupling reactions between two nucleophilic organometallic reagents and provides a new method for the formation of biaryl compounds. The successful development of this reaction was enabled by the use of commercially available 2,2-bis(diphenylphosphino)-1,1-binaphthyl (BINAP) as the ligand. A small amount of BINAP (3 mol %) was sufficient to suppress the formation of the homocoupling products, and the reaction yielded the cross-coupling products with high selectivity under mild conditions, even when the ratio of the two coupling partners was 1:1.

One-pot synthesis of poly(alkoxysilane)s by Si-Si/Si-O dehydrocoupling of silanes with alcohols using Group IV and VIII metallocene complexes

Si-Si/Si-O dehydrocoupling reactions of silanes with alcohols (1:1.5 mole ratio), catalyzed by Cp2MCl2/Red-Al (M=Ti, Zr) and Cp2M′ (M′=Co, Ni), produced poly(alkoxysilane)s in one-pot in high yield. The silanes included p-X-C6H4SiH3 (X=H, CH3, OCH3, F), PhCH2SiH3, and (PhSiH2)2. The alcohols were MeOH, EtOH, iPrOH, PhOH, and CF3(CF2) 2CH2OH. The weight average molecular weight of the poly(alkoxysilane)s ranged from 600 to 8000. The dehydrocoupling reactions of phenylsilane with ethanol (1:1.5 mole ratio) using Cp2HfCl2/Red-Al and phenylsilane with ethanol (1:3 mole ratio) using Cp2TiCl2/Red-Al gave only triethoxyphenylsilane as product.