344332-94-1

Basic information

• Product Name: 1-(3-Hydroxy-1-methyl-cyclohexyl)-2-methanesulfonyl-ethanone
• Synonyms: 1-(3-Hydroxy-1-methyl-cyclohexyl)-2-methanesulfonyl-ethanone
• CAS NO: 344332-94-1
• Molecular Weight: 234.317
• Mol File: 344332-94-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(3-Hydroxy-1-methyl-cyclohexyl)-2-methanesulfonyl-ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(3-Hydroxy-1-methyl-cyclohexyl)-2-methanesulfonyl-ethanone(344332-94-1)
• EPA Substance Registry System: 1-(3-Hydroxy-1-methyl-cyclohexyl)-2-methanesulfonyl-ethanone(344332-94-1)

Safety Data

• Hazardous Substances Data: 344332-94-1(Hazardous Substances Data)

Upstream product

• 67-71-0 dimethylsulfone 
• 64326-18-7 (±)-(1R,5S)-1-methyl-6-oxabicyclo[3.2.1]octan-7-one 
• 6493-80-7 methyl 1-methyl-3-cyclohexenecarboxylate 
• 85319-22-8 (1R,4R,5R)-4-Iodo-1-methyl-6-oxa-bicyclo[3.2.1]octan-7-one 
• 16646-42-7 1-methyl-3-cyclohexenecarboxylic acid 

Downstream Products

• 85319-31-9 Toluene-4-sulfonic acid (1R,5R)-5-methyl-6-oxo-bicyclo[3.2.1]oct-1-yl ester 
• 85319-23-9 3-(2-Methanesulfonyl-acetyl)-3-methyl-cyclohexanone 
• 85319-24-0 (1S,5S)-1-Hydroxy-7-methanesulfonyl-5-methyl-bicyclo[3.2.1]octan-6-one 

Relevant articles and documents

Enones with Strained Double Bonds. 8. The Bicyclooctane Systems

The bicyclic enones bicyclooct-1-en-3-one (4) and 1-methylbicyclooct-5(6)-en-7-one (5) have been generated from various precursors and trapped by the addition of nucleophiles such as MeOH, PhSeH, or H2O.The bridgehead enone 5 has also been trapped as its cycloadduct 31 with furan.Pyrolysis of this cycloadduct 31 reformed the bridgehead enone 5 that was trapped as the cycloadduct 32.Related bridgehead enones 35 and 47 have also been generated as intermediates leading to products with bridgehead methoxy substituents.